单原子催化剂在锂硫电池中的应用

陈超; 雷源; 林展; 张山青

doi:10.12052/gdutxb.230112

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单原子催化剂在锂硫电池中的应用

催化与能源材料 | 更新时间：2026-05-27

- 单原子催化剂在锂硫电池中的应用
- Single-atom Catalysts for Lithium-sulfur Batteries
- 广东工业大学学报 2023年40卷第6期页码：62-74
- 作者机构：
  
  1. 广东工业大学轻工化工学院,广东,广州,510006
  2. 化学与精细化工广东省实验室揭阳分中心,广东,揭阳,515200
- 作者简介：
  
  陈超 (1983–) ，男，副教授，工学博士，主要研究方向为纳米多孔材料的设计制备及其在能源和环境中的应用研究，E-mail：c.chen@gdut.edu.cn
- 基金信息：
  
  国家自然科学基金资助面上项目 (52171204)
- DOI：10.12052/gdutxb.230112
  中图分类号： TQ152;O643
- 网络首发：2023-11-25，
  
  纸质出版：2023
- 稿件说明：
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陈超, 雷源, 林展, 张山青. 单原子催化剂在锂硫电池中的应用[J]. 广东工业大学学报, 2023, 40(6): 62-74.

Chen Chao, Lei Yuan, Lin Zhan, et al. Single-atom Catalysts for Lithium-sulfur Batteries[J]. 2023, 40(6): 62-74.
陈超, 雷源, 林展, 张山青. 单原子催化剂在锂硫电池中的应用[J]. 广东工业大学学报, 2023, 40(6): 62-74. DOI： 10.12052/gdutxb.230112.

Chen Chao, Lei Yuan, Lin Zhan, et al. Single-atom Catalysts for Lithium-sulfur Batteries[J]. 2023, 40(6): 62-74. DOI： 10.12052/gdutxb.230112.

摘要

锂硫电池具有理论能量密度高、成本低、环境友好等优点，被认为是最有前景的下一代高能量密度电池之一。多硫化物的“穿梭效应”是阻碍锂硫电池商业化的关键问题。采用“催化”策略增强硫物种之间的氧化还原反应动力学已被证明是缓解“穿梭效应”的有效方法。单原子催化剂由于其均匀的金属活性中心、独特的电子特性和理论上100 %的金属原子利用效率，在催化领域得到了广泛关注。近年来，单原子催化剂被引入到锂硫电池体系中，以实现硫物种之间转化反应的快速动力学。本文以影响单原子催化剂活性的几个关键因素为主线，综述了单原子催化剂在锂硫电池领域应用的主要进展，并对锂硫电池用单原子催化剂的前景进行了展望。本文对未来设计制备高活性的锂硫电池用单原子催化剂提供了思路。

Abstract

Owing to advantages of high theoretical energy density

low cost and environmental friendliness

lithium-sulfur (Li-S) battery is considered as one of the most promising next-generation high-energy-density batteries. The "shuttle effect" of polysulfides is the key issue hindering the commercialization of Li-S batteries. Adoption of "catalytic" strategy to enhance the sulfur redox kinetics has been demonstrated to be an effective way to alleviate the "shuttle effect". Single-atom catalysts (SACs) have received much attention in the field of catalysis due to their uniform metal active centers

unique electronic properties

and theoretically 100% metal atom utilization. In recent years

SACs have been introduced into Li-S systems and studied to achieve fast sulfur conversion kinetics. In this research

the latest progress in the application of SACs in Li-S batteries was reviewed

with special emphasis on the discussion of key factors affecting the catalytic activity of SACs. The prospects of SACs for Li-S batteries were pointed out and highlighted. Important guidance is provided for future design and fabrication of high-performance SACs for Li-S battery application.

关键词

Keywords

references

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