高电压电解液添加剂在钴酸锂/石墨软包电池中的作用机理

王雅婷; 李健辉; 叶海平; 刘军; 施志聪

doi:10.12052/gdutxb.220190

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高电压电解液添加剂在钴酸锂/石墨软包电池中的作用机理

更新时间：2026-05-27

- 高电压电解液添加剂在钴酸锂/石墨软包电池中的作用机理
- The Working Mechanism of Additive in High Voltage Electrolyte for Lithium Cobaltate/Graphite Pouch Cell
- 广东工业大学学报 2023年40卷第3期页码：74-82
- 作者机构：
  
  1. 广东工业大学材料与能源学院,广东,广州,510006
  2. 华南师范大学化学学院,广东,广州,510006
- 作者简介：
  
  施志聪(1976–)，男，教授，博士，主要研究方向为新能源材料、新型电池、电化学测试技术，E-mail：zhicong@gdut.edu.cn
- 基金信息：
  
  科技部重点研发计划战略性科技创新合作项目(2022YFE0202400);珠海市科技创新局产学研合作项目(ZH22017001200059PWC);广东省科技厅国际合作项目(2019A050510043)
- DOI：10.12052/gdutxb.220190
  中图分类号： TM912
- 网络首发：2023-05-25，
  
  纸质出版：2023
- 稿件说明：
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王雅婷, 李健辉, 叶海平, 刘军, 施志聪. 高电压电解液添加剂在钴酸锂/石墨软包电池中的作用机理[J]. 广东工业大学学报, 2023, 40(3): 74-82.

Wang Ya-ting, Li Jian-hui, Ye Hai-ping, et al. The Working Mechanism of Additive in High Voltage Electrolyte for Lithium Cobaltate/Graphite Pouch Cell[J]. 2023, 40(3): 74-82.
王雅婷, 李健辉, 叶海平, 刘军, 施志聪. 高电压电解液添加剂在钴酸锂/石墨软包电池中的作用机理[J]. 广东工业大学学报, 2023, 40(3): 74-82. DOI： 10.12052/gdutxb.220190.

Wang Ya-ting, Li Jian-hui, Ye Hai-ping, et al. The Working Mechanism of Additive in High Voltage Electrolyte for Lithium Cobaltate/Graphite Pouch Cell[J]. 2023, 40(3): 74-82. DOI： 10.12052/gdutxb.220190.

摘要

3-三(2-氰氧基)丙烷(1

3-Tris(2-cyanoethoxy) propane，TPPN)作为一种新的电解液添加剂，可应用于4.55 V高电压钴酸锂(LiCoO

) /石墨软包电池。通过对比不含和含有TPPN添加剂的锂电池的循环性能，发现加入质量分数为2%的TPPN能大幅提高电池性能。3.00~4.55 V下以1C/1C倍率充放电，含有2%TPPN的电池在25℃下循环900周容量保持率为86.4%，而未添加TPPN的样品仅为8.7%。从理论计算和线性扫描数据可知，TPPN较电解液溶剂优先分解。从LiCoO

表面上X射线光电子能谱的N 1s谱可知，TPPN在钴酸锂表面形成界面膜。从阻抗数据可知，该界面膜具有低阻抗和高稳定性质。从理论计算、LiCoO

表面上扫描、透射电镜、X射线衍射谱和石墨表面上X射线光电子能谱的Co 2p谱可知，该界面膜能有效抑制电解液分解和钴离子的溶出，确认了界面膜的高稳定性质。

Abstract

3-Tris (2-cyanoethoxy) propane (TPPN) as a new electrolyte additive has been investigated in 4.55 V high voltage lithium cobaltate (LiCoO

) /graphite pouch cells. By comparing the cycle performance of cells without and with TPPN

it is found that the addition of TPPN can improve the performance

and the optimal weight proportion is 2%. At 3.00-4.55 V and 1C/1C

the cells with 2%TPPN has a capacity retention rate of 86.4% at 25℃ for 900 cycles compared with the capacity retention rate of 8.7% that without 2%TPPN. According to the theoretical calculation and linear sweep voltammetry

the decomposition of TPPN is preferred to tha

t of the electrolyte solvent. It can be seen from N 1s spectra from X-ray photoelectron spectroscopy on LiCoO

surface that TPPN forms an interfacial film on the LiCoO

surface. It can be seen from the impedance data that the interface film formed by TPPN has low impedance and high stability. From theoretical calculation

scanning

transmission electron microscopy

X-ray diffraction on LiCoO

surface and Co 2p spectra from X-ray photoelectron spectroscopy on graphite surface

it is revealed that the interface film formed by TPPN can effectively suppress the decomposition of electrolyte and the dissolution of cobalt ions

confirming the high stability of the interface film formed by TPPN.

关键词

Keywords

references

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