木质素基超疏水涂层的制备及其应用性能研究

刘雪; 刘忠明; 席跃宾; 王守娟; 孔凡功

doi:10.12052/gdutxb.210130

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木质素基超疏水涂层的制备及其应用性能研究

木质素科学与技术 | 更新时间：2026-05-27

- 木质素基超疏水涂层的制备及其应用性能研究
- A Study of Preparation and Application Performance of Lignin-based Superhydrophobic Coatings
- 广东工业大学学报 2022年39卷第1期页码：34-40, 134
- 作者机构：
  
  齐鲁工业大学(山东省科学院) 生物基材料与绿色造纸国家重点实验室,山东,济南,250353
- 作者简介：
  
  刘雪(1996–)，女，硕士研究生，主要研究方向为木质素基功能材料
  孔凡功(1976–)，男，教授，博士，博士生导师，主要研究方向为木质纤维基功能材料，E-mail：kfgwsj1566@163.com
- 基金信息：
  
  国家自然科学基金资助面上项目(31971605, 31800499);山东省重大科技创新工程资助项目(2019JZZY010407, 2019JZZY010304);山东省自然科学基金资助项目(ZR2020MC156);山东省科教产融合创新试点工程资助项目(2020KJC-ZD06，2020KJC-ZD13)
- DOI：10.12052/gdutxb.210130
  中图分类号： TQ352.7
- 纸质出版：2022
- 稿件说明：
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刘雪, 刘忠明, 席跃宾, 王守娟, 孔凡功. 木质素基超疏水涂层的制备及其应用性能研究[J]. 广东工业大学学报, 2022, 39(1): 34-40, 134.

Liu Xue, Liu Zhong-ming, Xi Yue-bin, et al. A Study of Preparation and Application Performance of Lignin-based Superhydrophobic Coatings[J]. 2022, 39(1): 34-40, 134.
刘雪, 刘忠明, 席跃宾, 王守娟, 孔凡功. 木质素基超疏水涂层的制备及其应用性能研究[J]. 广东工业大学学报, 2022, 39(1): 34-40, 134. DOI： 10.12052/gdutxb.210130.

Liu Xue, Liu Zhong-ming, Xi Yue-bin, et al. A Study of Preparation and Application Performance of Lignin-based Superhydrophobic Coatings[J]. 2022, 39(1): 34-40, 134. DOI： 10.12052/gdutxb.210130.

摘要

超疏水涂层由于其广泛的应用前景

近年来备受关注。然而

利用天然聚合物制备超疏水材料和超疏水涂层仍然缺乏一种简单、经济的方法。本文通过取代反应制备了超疏水性木质素-PFTEOS粉体。由于该粉体与基体无关的特性和优异的超疏水性

可用于各种基体制备超疏水性涂层。所制备的涂层疏水性极强

水接触角最高可达169°

同时具有良好的耐摩擦、耐酸碱、耐盐性能和较好的耐腐蚀性能：经砂纸摩擦循环20次或在1 mol/L HCl、0.20 mol/L NaOH和1 mol/L NaCl溶液中浸泡30 min后

涂层仍保持超疏水性能

且接触角大于150°。这种低成本、可降解和可扩展的木质素基涂层在不同领域具有巨大的应用潜力

并为碱木质素的增值利用提供了一种简单的方法。

Abstract

Superhydrophobic coatings have drawn much attention in recent years for their wide potential applications. However

a simple and cost-effective approach is still needed for preparing superhydrophobic materials and coatings using natural polymer. Herein

a hierarchical superamphiphobic Lignin-PFTEOS powder was prepared via a substitution reaction. Owing to the substrate-independent characteristics and excellent super-repellency of the powder

it could be applied to various substrates to fabricate superhydrophobic coatings. The prepared coatings have a huge repellency to water

with a water contact angle of 169°

as well as good friction resistance

acid resistance

alkali resistance

salt resistance properties and quite good corrosion resistance performance. After 20 cycles of sand friction or being immersed in 1 mol/L HCl

0.20 mol/L NaOH and 1 mol/L NaCl solution for 30 minutes

the coatings still retain superhydrophobic capability

with contact angle higher than 150°. Due to its low cost

biodegradability and scalability

lignin-based coatings have huge potential applications in different fields and provide a simple method for the value-added utilization of alkali lignin.

关键词

Keywords

references

XU Q Y, BAI Y Y, ZHAO X, et al . Synthesis and characterization of an amphiphilic lignin-based cationic surfactant [J ] . Industrial Crops and Products, 2021, 164: 113376.

YOU X Y, WANG X L, ZHANG H J, et al . Supertough lignin hydrogels with multienergy dissipative structures and ultrahigh antioxidative activities [J ] . ACS Applied Materials and Interfaces, 2020, 12(35): 39892-39901.

ZHANG X, LIU W F, CAI J Q, et al . Equip the hydrogel with armor: strong and super tough biomass reinforced hydrogels with excellent conductivity and anti-bacterial performance [J ] . Journal of Materials Chemistry A, 2019, 7(47): 26917-26926.

LIU W F, FANG C, CHEN F T, et al . Strong, r eusable, and self-healing lignin-containing polyurea adhesives [J ] . ChemSusChem, 2020, 13(17): 4691-4701.

MORENO A, MORSALI M, LIU J R, et al . Access to tough and transparent nanocomposites via Pickering emulsion polymerization using biocatalytic hybrid lignin nanoparticles as functional surfactants [J ] . Green Chemistry, 2021, 23(8): 3001-3014.

THAKUR V K, THALUR M K, RAGHAVAN P, et al . Progress in green polymer composites from lignin for multifunctional applications: a review [J ] . ACS Sustainable Chemistry Engineering, 2014, 2(5): 1072-1092.

WU B R, CUI X, JIANG H Y, et al . A superhydrophobic coating harvesting mechanical robustness, passive anti-icing and active de-icing performances [J ] . Journal of Colloid Interface Science, 2021, 590: 301-310.

ZHANG D J, WU G Q, LI H, et al . Superamphiphobic surfaces with robust self-cleaning, abrasion resistance and anti-corrosion [J ] . Chemical Engineering Journal, 2021, 406: 126753.

LIU Z Y, ZHANG C Y, ZHANG X G, et al . Durable superhydrophobic PVDF/FEVE/GO@TiO 2 composite coating with excellent anti-scaling and UV resistance properties [J ] . Chemical Engineering Journal, 2021, 411: 128632.

XIAO L J, DENG M, ZENG W G, et al . Novel robust superhydrophobic coating with self-cleaning properties in air and oil based on rare earth metal oxide [J ] . Industrial Engineering Chemistry Research, 2017, 56(43): 12354-12361.

PASSAUER L, HALLAS T, BÄUCKER E, et al . Biodegradation of hydrogels from oxyethylated lignins in model soils [J ] . ACS Sustainable Chemistry Engineering, 2015, 3(9): 1955-1964.

GUO J Q, FANG W W, WELLE A, et al . Superhydrophobic and slippery lubricant-infused flexible transparent nanocellulose films by photoinduced thiol-ene functionalization [J ] . ACS Applied Materials and Interfaces, 2016, 8(49): 34115-34122.

MONTEIL-RIVERA F, PHUONG M, YE M W, et al . Isolation and characterization of herbaceous lignins for applications in biomaterials [J ] . Industrial Crops and Products, 2013, 41: 356-364.

YU M D, MISHRA D, CUI Z Y, et al . Recycling papermill waste lignin into recyclable and flowerlike composites for effective oil/water separation [J ] . Composites Part B:Engineering, 2021, 216: 108884.

WANG H, XIONG F Q, TAN Y J, et al . Preparation and formation mechanism of covalent–noncovalent forces stabilizing lignin nanospheres and their application in superhydrophobic and carbon materials [J ] . ACS Sustainable Chemistry Engineering, 2021, 9(10): 3811-3820.

ORIBAYO O, FENG X S, REMPEL G L, et al . Synthesis of lignin-based polyurethane/graphene oxide foam and its application as an absorbent for oil spill clean-ups and recovery [J ] . Chemical Engineering Journal, 2017, 323: 191-202.

FENG L, LI S, LI Y, et al . Super-hydrophobic surfaces: from natural to artificial [J ] . Advanced materials, 2002, 14(24): 1857-1860.

LI D C, XU W F, CHENG H Y, et al . One-step thermochemical conversion of biomass waste into superhydrophobic carbon material by catalytic pyrolysis [J ] . Global Challenges, 2020, 4(4): 1900085.

ZHANG Y Q, WANG X A, WANG X, et al . Preparation and characterization of lignin-based superhydrophobic coatings [J ] . Transactions of China Pulp and Paper, 2019, 34(3): 18-23.

顾俐慧. 木质纤维素纳米纤丝基超疏水材料的制备与表征[D]. 南京: 南京林业大学, 2019.

YU C H, WANG F, FU S Y, et al . Laccase-assisted grafting of acrylic acid onto lignin for its recovery from wastewater [J ] . Journal of Polymers and the Environment, 2016, 25(4): 1072-1079.

SANTOS R B, CAPANEMA E A, BALAKSHIN M Y, et al . Lignin structural variation in hardwood species [J ] . Journal of Agricultural and Food Chemistry, 2012, 60(19): 4923-4930.

HUANG Y X, WANG Z X, HOU D Y, et al . Coaxially electrospun super-amphiphobic silica-based membrane for anti-surfactant-wetting membrane distillation [J ] . Journal of Membrane Science, 2017, 531: 122-128.

GUO K, SHARMA A, TOH R J, et al . Porous silicon nanostructures as effective faradaic electrochemical sensing platforms [J ] . Advanced Functional Materials, 2019, 29(24): 1809206.

ZHANG Y J, CHEN H L, WANG S J, et al . A new lamellar larch-based carbon material: fabrication, electrochemical characterization and supercapacitor applications [J ] . Industrial Crops and Products, 2020, 148: 112306.

ZHANG Y J, CHEN H L, WANG S J, et al . Facile fabrication and structure control of SiO 2 /carbon via in situ doping from liquefied bio-based sawdust for supercapacitor applications [J ] . Industrial Crops and Products, 2020, 151: 112490.

BAHRPAIMA K, FATEHI P. Synthesis and characterization of carboxyethylated lignosulfonate [J]. ChemSusChem, 2018, 11(17): 2967-2980.

ZONG E M, LIU X H, LIU L N, et al . Graft polymerization of acrylic monomers onto lignin with CaCl 2 –H 2 O 2 as initiator: preparation, mechanism, characterization, and application in poly(lactic acid) [J ] . ACS Sustainable Chemistry and Engineering, 2017, 6(1): 337-348.

YE H, ZHU L Q, LI W P, et al . Constructing fluorine-free and cost-effective superhydrophobic surface with normal-alcohol-modified hydrophobic SiO 2 nanoparticles [J ] . ACS Applied Materials and Interfaces, 2017, 9(1): 858-867.

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