木质素基可降解复合膜材料的研究进展

郝艳平; 罗通; 吕高金; 王超; 周昊; 杨桂花; 陈嘉川

doi:10.12052/gdutxb.210128

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木质素基可降解复合膜材料的研究进展

木质素科学与技术 | 更新时间：2026-05-27

- 木质素基可降解复合膜材料的研究进展
- Research Progress of Lignin-derived Biodegradable Composite Film Materials
- 广东工业大学学报 2022年39卷第1期页码：21-33
- 作者机构：
  
  1. 齐鲁工业大学(山东省科学院) 生物基材料与绿色造纸国家重点实验室,山东,济南,250353
  2. 日照金禾生化集团股份有限公司,山东,日照,276800
- 作者简介：
  
  郝艳平(1998–)，女，硕士研究生，主要研究方向为木质素化学及其复合功能材料
  吕高金(1984–)，男，教授，主要研究方向为生物质资源高值化利用、木质素化学与化工，E-mail：gaojinlv@qlu.edu.cn
- 基金信息：
  
  国家自然科学基金资助项目(31770630)
- DOI：10.12052/gdutxb.210128
  中图分类号： TQ314.1
- 纸质出版：2022
- 稿件说明：
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郝艳平, 罗通, 吕高金, 王超, 周昊, 杨桂花, 陈嘉川. 木质素基可降解复合膜材料的研究进展[J]. 广东工业大学学报, 2022, 39(1): 21-33.

Hao Yan-ping, Luo Tong, Lyu Gao-jin, et al. Research Progress of Lignin-derived Biodegradable Composite Film Materials[J]. 2022, 39(1): 21-33.
郝艳平, 罗通, 吕高金, 王超, 周昊, 杨桂花, 陈嘉川. 木质素基可降解复合膜材料的研究进展[J]. 广东工业大学学报, 2022, 39(1): 21-33. DOI： 10.12052/gdutxb.210128.

Hao Yan-ping, Luo Tong, Lyu Gao-jin, et al. Research Progress of Lignin-derived Biodegradable Composite Film Materials[J]. 2022, 39(1): 21-33. DOI： 10.12052/gdutxb.210128.

摘要

传统塑料薄膜制品的不可降解性所带来的环境和社会问题日渐凸显

促使了生物基可降解、可再生膜材料的发展。木质素是一种储量最丰富的天然芳香族聚合物

近年来研究人员将其与其他聚合物复合

制备具有特定功能的高附加值可降解膜材料

取得了许多重大成果。本文从可持续发展的角度

首先介绍了木质素的结构、化学特性及分离方式; 其次综述了木质素基可降解复合膜材料的制备及其在可降解地膜、包装材料、传感器响应材料、抗菌和紫外防护等方面应用的最新进展。并讨论了木质素基生物可降解复合膜材料面临的主要问题

为今后环境友好型木质素基功能膜材料的制备及应用提供一定参考。

Abstract

The non-degradability of traditional plastic film products leads to serious environmental and social issues

which promotes the development of biodegradable composite film materials. Recent advances in abundant natural polymeric materials with different structural properties and excellent biodegradability were presented. Lignin

as the most abundant aromatic polymer

is considered a promising choice to manufacture multifarious advanced and functional film materials. From the perspective of sustainable development

the structure

chemical characteristics

fractionation methods of lignin are first introduced

and then a review focuses on the preparation of biodegradable composite film material and recent progress of lignin-derived biodegradable film materials with designed functionalities for different applications

such as degradable plastic film material

packaging materials

sensor response materials

antibacterial

and UV protection. Finally

the main problems faced by lignin-based biodegradable composite film materials are discussed

and the potential development directions for environmental-friendly lignin-based functional membrane materials in the future are proposed.

关键词

Keywords

references

LI L, LUO Y, LI R, et al . Effective uptake of submicrometre plastics by crop plants via a crack- entry mode [J ] . Nature Sustainability, 2020, 3(11): 929-937.

WANG Q, ZHENG C, ZHANG J, et al . Insights into the adsorption of Pb(II) over trimercapto-s-triazine trisodium salt-modified lignin in a wide pH range [J ] . Chemical Engineering Journal Advances, 2020, 1: 100002.

LU Y, WEI X Y, ZONG Z M, et al . Structural investigation and application of lignins [J ] . Progress in Chemistry, 2013, 25(5): 838-858.

YANG W, FORTUNATI E, GAO D, et al . Valorization of acid isolated high yield lignin nanoparticles as innovative antioxidant/antimic- robial organic materials [J ] . ACS Sustainable Chemistry Engineering, 2018, 6(3): 3502-3514.

LI C, CHEN C, WU X, et al . Recent advancement in lignin biorefinery: with special focus on enzymatic degradation and valorization [J ] . Bioresource Technology, 2019, 291: 121898.

BRAZIL T R, GONCALVES M, JUNIOR M S O, et al . A statistical approach to optimize the activated carbon production from Kraft lignin based on conventional and microwave processes [J ] . Microporous and Mesoporous Materials, 2020, 308: 110485.

YU O, KIM K H. Lignin to materials: a focused review on recent novel lignin applications [J]. Applied Sciences, 2020, 10(13): 4626.

DORRESTIJN E, LAARHOVEN L J J, ARENDS I W C E, et al . The occurrence and reactivity of phenoxyl linkages in lignin and low rank coal [J ] . Journal of Analytical and Applied Pyrolysis, 2000, 54(1): 153-192.

SAJJADI M, AHMADPOOR F, NASROLLAHZADEH M, et al . Lignin-derived (nano)materials for environmental pollution remediation: current challenges and future perspectives [J ] . International Journal of Biological Macro molecules, 2021, 178: 394-423.

雷鸣. 木质素结构单元间主要化学键连接在热解过程的断裂与重组机制研究[D]. 广州: 华南理工大学, 2019.

CHIO C, SAIN M, QIN W. Lignin utilization: a review of lignin depolymerization from various aspects [J]. Renewable and Sustainable Energy Reviews, 2019, 107: 232-249.

LU F, YUE F. Lignin: biosynthesis, functions and economic significance [M]. New York: Nova Science Publishers, Inc. , 2019.

YUE F X, LIN M S, QIAN Y, et al . Recent advances of anti-UV radiation of lignin [J ] . Journal of Forestry Engineering, 2021, 6(2): 12-20.

马艾丽. 木质素高值化材料的制备与应用性能研究[D]. 广州: 华南理工大学, 2014.

RICHTER A P, BROWN J S, BHARTI B, et al . An environmentally benign antimicrobial nanoparticle based on a silver-infused lignin core [J ] . Nature Nanotechnology, 2015, 10(9): 817-823.

LI P, LYU W, AI S. Green and gentle synthesis of Cu 2 O nanoparticles using lignin as reducing and capping reagent with antibacterial properties [J ] . Journal of Experimental Nanoscience, 2016, 11(1): 18-27.

CERRUTTI B, MORAES M L, PULCINELLI S, et al . Lignin as immobilization matrix for HIV p17 peptide used in immunosensing [J ] . Biosensors bioelectronics, 2015, 71: 420-426.

DURING A, DEBOUCHE C, RAAS T, et al . Among plant lignans, pinoresinol has the strongest antiinflammatory properties in human intestinal Caco-2 cells [J ] . The Journal of nutrition, 2012, 142(10): 1798-1805.

FIGUEIREDO P, LINTINEN K, HIRVONEN J T, et al . Properties and chemical modifications of lignin: towards lignin-based nanomaterials for biomedical applications [J ] . Progress in Materials Science, 2018, 93: 233-269.

YANG J Y, BI Y T, WU J X, et al . Research advances in chemical modification of lignin [J ] . Journal of Shanghai Institute of Technology(Natural Science), 2015, 15(1): 29-39.

LAURICHESSE S, AVÉROUS L. Chemical modification of lignins: towards biobased polymers [J]. Progress in Polymer Science, 2014, 39(7): 1266-1290.

WEN J L, CHEN T Y, SUN R C. Research progress on separation and structural analysis of lignin in lignocellulosic biomass [J]. Journal of Forestry Engineering, 2017, 2(5): 76-84.

HU Z, YEH T F, CHANG H M, et al . Elucidation of the structure of cellulolytic enzyme lignin [J ] . Holzforschung, 2006, 60(4): 389-397.

WU S, ARGYROPOULOS D. An improved method for isolating lignin in high yield and purity [J]. Journal of Pulp and Paper Science, 2003, 29(7): 235-240.

CHEN T Y, WANG B, WU Y, et al . Structural variations of lignin macromolecule from different growth years of Triploid of Populus tomentosa Carr [J ] . International Journal of Biological Macromolecules, 2017, 101: 747-757.

LU Y, LU Y C, HU H Q, et al . Structural characterization of lignin and its degradation products with spectroscopic methods [J ] . Journal of Spectroscopy, 2017, 2017: 1-15.

SU X R, FU Y J, LI Z Q, et al . Research progress on extraction and high-value application of lignin [J ] . Journal of Dalian Polytechnic University, 2021, 40(2): 107-115.

LI L F, HU Y C. Application of ionic liquids in lignin processing [J]. Chemistry and Industry of Forest Products, 2015, 35(2): 163-170.

TAN Y T, NGOH G C, CHUA A S M. Effect of functional groups in acid constituent of deep eutectic solvent for extraction of reactive lignin [J]. Bioresource Technology, 2019, 281: 359-366.

ZHANG Z, XIN L, QI J, et al . Selective electro-conversion of glycerol to glycolate on carbon nanotube supported gold catalyst [J ] . Green Chemistry, 2012, 14(8): 2150-2152.

WANG B K, SHENG L P, SHU Y, et al . Research progress of lignin-based biodegradable polymer composites [J ] . Journal of Shaoyang University(Natural Science Edition), 2020, 17(1): 73-80.

WANG H M, YUAN T Q, SONG G Y, et al . Advanced and versatile lignin-derived biodegradable composite film materials toward a sustainable world [J ] . Green Chemistry, 2021, 23(11): 3790-3817.

ZHU J, CHEN H, LU K, et al . Recent progress on starch-based biodegradable materials [J ] . Acta Polymerica Sinica, 2020, 51(9): 983-995.

JIMÉNEZ A, FABRA M J, TALENS P, et al . Edible and biodegradable starch films: a review [J ] . Food and Bioprocess Technology, 2012, 5(6): 2058-2076.

SHI R, LI B. Synthesis and characterization of cross-linked starch/lignin film [J]. Starch-Stärke, 2016, 68(11-12): 1224-1232.

LYU X Y, CAO W H, YANG Y J, et al . Preparation and characterization of starch/lignin composite films [J ] . Guangdong Chemical Industry, 2017, 44(20): 18-19.

BHAT R, ABDULLAH N, DIN R H, et al . Producing novel sago starch based food packaging films by incorporating lignin isolated from oil palm black liquor waste [J ] . Journal of Food Engineering, 2013, 119(4): 707-713.

MUJTABA M, MORSI R E, KERCH G, et al . Current advancements in chitosan-based film production for food technology:a review [J ] . International Journal of Biological Macromolecules, 2019, 121: 889-904.

CHEN L, TANG C Y, NING N Y, et al . Preparation and properties of chitosan/lignin composite films [J ] . Chinese Journal of Polymer Science, 2009, 27(5): 739-746.

YANG W, OWCZAREK J S, FORTUNATI E, et al . Antioxidant and antibacterial lignin nanoparticles in polyvinyl alcohol/c hitosan films for active packaging [J ] . Industrial Crops and Products, 2016, 94: 800-811.

SU L, LI S S, FANG G Z. Preparation and performance of alkali lignin/chitosan reaction film [J]. Journal of Functional Materials, 2013, 44(9): 1353-1358.

DUAN Y, FREYBURGER A, KUNZ W, et al . Lignin/chitin films and their adsorption characteristics for heavy metal Ions [J ] . ACS Sustainable Chemistry Engineering, 2018, 6(5): 6965-6973.

AVEROUS L. Handbook of biopolymers and biodegradable plastics [M]. Amsterdam: William Andrew, 2013: 171.

YANG Y, ZHANG L, XIONG Z, et al . Research progress in the heat resistance, toughening and filling modification of PLA [J ] . Science China Chemistry, 2016, 59(11): 1355-1368.

LI X, HEGYESI N, ZHANG Y, et al . Poly(lactic acid)/lignin blends prepared with the Pickering emulsion template method [J ] . European Polymer Journal, 2019, 110: 378-384.

MU C Y, XUE L Y, ZHU J, et al . Mechanical and thermal properties of toughened poly(L-lactic) acid and lignin blends [J ] . BioResources, 2014, 9(3): 5557-5566.

GORDOBIL O, EGÜÉS I, LLANO-PONTE R, et al . Physicochemical properties of PLA lignin blends [J ] . Polymer Degradation and Stability, 2014, 108: 330-338.

GORDOBIL O, EGÜÉS I, LABIDI J. Modification of Eucalyptus and Spruce organosolv lignins with fatty acids to use as filler in PLA [J]. Reactive and Functional Polymers, 2016, 104: 45-52.

SHANKAR S, RHIM J-W, WON K. Preparation of poly(lactide)/lignin/silver nanoparticles composite films with UV light barrier and antibacterial properties [J]. International Journal of Biological Macromolecules, 2018, 107: 1724-1731.

贺晓艳. 改性纳米木质素增强可降解聚合物薄膜性能研究[D]. 哈尔滨: 东北林业大学, 2019.

WANG X, BIAN H, NI S, et al . BNNS/PVA bilayer composite film with multiple-improved properties by the synergistic actions of cellulose nanofibrils and lignin nanoparticles [J ] . International Journal of Biological Macromolecules, 2020, 157: 259-266.

苏玲. 碱木质素-PVA基交联薄膜的制备与性能研究[D]. 哈尔滨: 东北林业大学, 2015.

JIANG L, YE D Z, ZHANG M H, et al . Structure and properties of lignosulfonate calcium/polyvinyl alcohol blends [J ] . Polymer Materials Science and Engineering, 2015, 31(5): 32-38.

ZHANG X, LIU W, LIU W, et al . High performance PVA/lignin nanocomposite films with excellent water vapor barrier and UV-shielding properties [J ] . International Journal of Biological Macromolecules, 2020, 142: 551-558.

POSOKNISTAKUL P, TANGKRAKUL C, CHAOSUANPHAE P, et al . Fabrication and characterization of lignin particles and their ultraviolet protection ability in PVA composite film [J ] . ACS Omega, 2020, 5(33): 20976-20982.

LUO T, WANG C, JI X, et al . Innovative production of lignin nanoparticles using deep eutectic solvents for multifunctional nanocomposites [J ] . International Journal of Biological Macromolecules, 2021, 183: 781-789.

CHEN S H, LI T. Industry statue development prospects of biodegradable plastics [J]. Modern Plastics Processing and Applications, 2020, 32(2): 50-54.

WATTANAWONG N, AHT-ONG D. Antibacterial activity, thermal behavior, mechanical properties and biodegradability of silver zeolite/poly(butylene succinate) composite films [J]. Polymer Degradation and Stability, 2021, 183: 109459.

KHAN H, KAUR S, BALDWIN T C, et al . Effective control against broadleaf weed species provided by biodegradable PBAT/PLA mulch film embedded with the Herbicide 2-methyl-4-chlorophenoxyacetic acid (MCPA) [J ] . ACS Sustainable Chemistry Engineering, 2020, 8(13): 5360-5370.

ZHANG Y, ZHOU S, FANG X, et al . Renewable and flexible UV-blocking film from poly(butylene succinate) and lignin [J ] . European Polymer Journal, 2019, 116: 265-274.

LIU L, HUANG G, SONG P, et al . Converting industrial alkali lignin to biobased functional additives for improving fire behavior and smoke suppression of polybutylene succinate [J ] . ACS Sustainable Chemistry Engineering, 2016, 4(9): 4732-4742.

QIU S, ZHOU Y, WATERHOUSE G I N, et al . Optimizing interfacial adhesion in PBAT/PLA nanocomposite for biodegradable packaging films [J ] . Food Chemistry, 2021, 334: 127487.

XIONG S J, PANG B, ZHOU S J, et al . Economically competitive biodegradable PBAT/lignin composites: effect of lignin methylation and compatibilizer [J ] . ACS Sustainable Chemistry Engineering, 2020, 8(13): 5338-5346.

XING Q, RUCH D, DUBOIS P, et al . Biodegradable and high-performance poly(butylene adipate-co-terephthalate)-lignin UV-blocking films [J ] . ACS Sustainable Chemistry Engineering, 2017, 5(11): 10342-10351.

XING Q, BUONO P, RUCH D, et al . Biodegradable UV-blocking films through core–shell lignin–melanin nanoparticles in poly(butylene adipate-co-terephthalate) [J ] . ACS Sustainable Chemistry Engineering, 2019, 7(4): 4147-4157.

ZHAO X, CHANG J. Progress in research and application of ε -caprolactone and polycaprolactone [J ] . Coal and Chemical Industry, 2021, 44(4): 130-134.

CHENG P F, LIANG M, YUN X Y, et al . Biodegradable blend films of poly( ε -caprolactone)/poly(propylene carbonate) for shelf life extension of whole white button mushrooms [J ] . Journal of Food Science and Technology, 2021, 6: 1-13.

OUYANG W Z, HUANG Y. Cellulolytic enzyme lignin efficiently blended with polycaprolactone: thermal, mechanical properties and morphological evaluation [J]. Advanced Materials Research, 2014, 1070-1072: 100-106.

王飞. 木质素/聚己内酯降解塑料的制备及性能研究[D]. 绵阳: 西南科技大学, 2015.

YANG W, QI G, DING H, et al . Biodegradable poly (lactic acid)-poly ( ε -caprolactone)-nanolignin composite films with excellent flexibility and UV barrier performance [J ] . Composites Communications, 2020, 22: 100497.

ZHANG Y, LIAO J, FANG X C, et al . Renewable high-performance polyurethane bioplastics derived from lignin-poly(ε-caprolactone) [J ] . ACS Sustainable Chemistry Engineering, 2017, 5(5): 4276-4284.

YONG J, CHENG Y, ZHOU H Y. Advances in researches of the mulch-film degradation and the underlying mechanism [J]. Chinese Journal of Applied Ecology, 2021, 32(2): 729-736.

JIN T, XUE Y H, ZHANG M M, et al . Research advances in regulations, standards and recovery of mulch film [J ] . Ecology and Environmental Sciences, 2020, 29(2): 411-420.

CHEN F S, WANG S. Study on environmentally friendly lignin based mulching films [J]. Paper Science Technology, 2014, 33(2): 88-91.

ZHANG Y, WANG J, FANG X, et al . High solid content production of environmentally benign ultra-thin lignin-based polyurethane films: Plasticization and degradation [J ] . Polymer, 2019, 178: 121572.

KANG Z Y, YANG H X. A brief analysis of safety concerns for plastic food packaging materials in China [J]. China Plastics, 2018, 32(10): 13-19.

RAI S, DUTTA P, MEHROTRA G. Lignin incorporated antimicrobial chitosan film for food packaging application [J]. Journal of Polymer Materials, 2017, 34: 171-183.

SHANKAR S, REDDY J P, RHIM J W. Effect of lignin on water vapor barrier, mechanical, and structural properties of agar/lignin composite films [J]. International Journal of Biological Macromolecules, 2015, 81: 267-273.

RUKMANIKRISHNAN B, RAJASEKHARAN S K, LEE J, et al . K-Carrageenan/lignin composite films: biofilm inhibition, antioxidant activity, cytocompatibility, UV and water barrier properties [J ] . Materials Today Communications, 2020, 24: 101346.

WANG J, DENG H Y, Qian Y, et al . Reduction of lignin color via one-step UV irradiation [J ] . Green Chemistry, 2015, 18(3): 695-699.

KAI D, TAN M, CHEE P L, et al . Towards lignin-based functional materials in a sustainable world [J ] . Green Chemistry, 2016, 18(5): 1175-1200.

WANG J Y, FANG X C, BAI F D, et al . Preparation and properties of biodegradable polycaprolactone grafted lignin films [J ] . Journal of East China University of Science and Technology, 2020, 46(4): 472-479.

QIAN Y, ZHONG X W, LI Y, et al . Fabrication of uniform lignin colloidal spheres for developing natural broad-spectrum sunscreens with high sun protection factor [J ] . Industrial Crops and Products, 2017, 101: 54-60.

WU W, LIU T, DENG X, et al . Ecofriendly UV-protective films based on poly(propylene carbonate) biocomposites filled with TiO 2 decorated lignin [J ] . International Journal of Biological Macromolecules, 2019, 126: 1030-1036.

徐冠豪. 麦草碱木质素/聚乙烯醇共混膜材料的制备与表征[D]. 哈尔滨: 东北林业大学, 2014.

HUANG J, WANG S, LYU S. Facile preparation of a robust and durable superhydrophobic coating using biodegradable lignin-coated cellulose nanocrystal particles [J]. Materials (Basel), 2017, 10(9): 1080.

LANDAETA E, ISAACS M, SCHREBLER R, et al . Enhanced photostability of cuprous oxide by lignin films on glassy carbon electrodes in th e transformation of carbon dioxide [J ] . Green Chemistry, 2018, 20: 2356-2364.

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