聚酰亚胺基复合材料在电池电极中的研究进展

刘存生; 刘屹东; 廖松义; 黄兴文; 李清玲; 宋道远; 闵永刚

doi:10.12052/gdutxb.210060

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聚酰亚胺基复合材料在电池电极中的研究进展

更新时间：2026-05-27

- 聚酰亚胺基复合材料在电池电极中的研究进展
- Research Progress of Polyimide-based Composite Materials in Battery Electrodes
- 广东工业大学学报 2022年39卷第3期页码：125-132
- 作者机构：
  
  1. 广东工业大学材料与能源学院,广东,广州,510006
  2. 仲恺农业工程学院化学化工学院,广东,广州,510225
  3. 深圳市凌盛电子有限公司,广东,深圳,518000
- 作者简介：
  
  刘存生(1998–)，男，硕士研究生，主要研究方向为锂离子电池材料制备
  廖松义(1990–)，男，副教授，博士，主要研究方向为锂离子电池材料的制备及其性能，E-mail：songyiliao@gdut.edu.cn
  闵永刚(1963–)，男，教授，博士，主要研究方向为有机光电功能材料与器件、高性能聚合物材料等，E-mail：ygmin@gdut.edu.cn
- 基金信息：
  
  科技部国家重点研发计划项目(2020YFB0408100);国家自然科学基金资助项目(U20A20340)
- DOI：10.12052/gdutxb.210060
  中图分类号： TQ323.7;TM911
- 纸质出版：2022
- 稿件说明：
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刘存生, 刘屹东, 廖松义, 黄兴文, 李清玲, 宋道远, 闵永刚. 聚酰亚胺基复合材料在电池电极中的研究进展[J]. 广东工业大学学报, 2022, 39(3): 125-132.

Liu Cun-sheng, Liu Yi-dong, Liao Song-yi, et al. Research Progress of Polyimide-based Composite Materials in Battery Electrodes[J]. 2022, 39(3): 125-132.
刘存生, 刘屹东, 廖松义, 黄兴文, 李清玲, 宋道远, 闵永刚. 聚酰亚胺基复合材料在电池电极中的研究进展[J]. 广东工业大学学报, 2022, 39(3): 125-132. DOI： 10.12052/gdutxb.210060.

Liu Cun-sheng, Liu Yi-dong, Liao Song-yi, et al. Research Progress of Polyimide-based Composite Materials in Battery Electrodes[J]. 2022, 39(3): 125-132. DOI： 10.12052/gdutxb.210060.

摘要

聚酰亚胺(Polyimide，PI)是一种以二酐和二胺为原料，热亚胺化后合成的聚合物。PI作为电池电极材料，具有理论容量高、机械强度大和易于回收的优点，但是它的绝缘性限制了内部活性位点的利用率，导致电池的倍率性能较差。本文综述了通过构建共轭结构来提高结构稳定性和引入羰基结构增加PI氧化还原中心(C=O)位点，以获得更高电池容量的研究策略，介绍了碳化PI和与石墨烯、碳纳米管的杂化以及使用静电纺丝工艺对PI作为电池电极的电化学性能的改进，对基于PI的其他复合材料的研究进行了总结，并对目前PI的研究方向进行了展望。

Abstract

Polyimide (PI) is a polymer synthesized by thermal imination of dianhydride and diamine as raw materials. As a battery electrodes material

it boasts high theoretical capacity

high mechanical strength and easy recovery. However

its insulation limits the utilization rate of internal active sites

resulting in poor rate performance of the battery. A research review is conducted concerning the improvement of the structural stability through enlarging conjugate structure and the introduction of more carbonyl structure (C=O) to increase PI redox center site. In order to obtain higher battery capacity

carbide and graphene combination

the hybridization of carbon nanotubes and the electrostatic spinning process are applied to improve electrochemical performance of battery electrode. The research of other materials based on PI is summarized as well. And the current research direction of PI is prospected.

关键词

Keywords

references

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