羟基自由基高级氧化技术应用进展综述

潘继生; 邓家云; 张棋翔; 阎秋生

doi:10.12052/gdutxb.180121

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羟基自由基高级氧化技术应用进展综述

综合研究 | 更新时间：2026-05-27

- 羟基自由基高级氧化技术应用进展综述
- A Review of the Application of Advanced Oxidation Technology of Hydroxyl Radicals
- 广东工业大学学报 2019年36卷第2期页码：70-77, 85
- 作者机构：
  
  广东工业大学　机电工程学院,广东,广州,510006
- 作者简介：
  
  潘继生(1980–)，男，副教授，博士，硕士生导师，主要研究方向为超精密加工与制造技术、光电晶片平坦化加工工艺、磁流变抛光技术、智能材料开发与应用
- 基金信息：
  
  NSFC−广东联合基金资助项目(U1801259);广东省科技计划项目(2016A010102014)
- DOI：10.12052/gdutxb.180121
  中图分类号： TQ031.7
- 网络首发：2019-03-15，
  
  纸质出版：2019
- 稿件说明：
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潘继生, 邓家云, 张棋翔, 阎秋生. 羟基自由基高级氧化技术应用进展综述[J]. 广东工业大学学报, 2019, 36(2): 70-77, 85.

Pan Ji-sheng, Deng Jia-yun, Zhang Qi-xiang, et al. A Review of the Application of Advanced Oxidation Technology of Hydroxyl Radicals[J]. 2019, 36(2): 70-77, 85.
潘继生, 邓家云, 张棋翔, 阎秋生. 羟基自由基高级氧化技术应用进展综述[J]. 广东工业大学学报, 2019, 36(2): 70-77, 85. DOI： 10.12052/gdutxb.180121.

Pan Ji-sheng, Deng Jia-yun, Zhang Qi-xiang, et al. A Review of the Application of Advanced Oxidation Technology of Hydroxyl Radicals[J]. 2019, 36(2): 70-77, 85. DOI： 10.12052/gdutxb.180121.

摘要

羟基自由基(•OH)是活跃性、进攻性最强的活性氧分子

具有非常高的反应速率常数、电负性和极强的氧化电极电位

利用•OH作为氧化剂的高级氧化技术具有广阔的应用前景. 本文从•OH的产生方法及基本原理出发

介绍了芬顿法、电芬顿法、紫外光催化氧化剂法、超声氧化法及其他复合方法的原理及其优缺点. 最后综述了以上方法在污水处理、土壤修复、垃圾渗滤液处理、重金属络合物处理以及光学材料超精密加工等方面的应用进展及应用局限.

Abstract

Hydroxyl radical (·OH) is the most active and aggressive molecule with very high reaction rate constant

electronegativity and strong oxidation electrode potential. The advanced oxidation technology using ·OH as oxidant has broad application prospects. Starting from the production method and basic principle of ·OH

the principles

advantages and disadvantages of Fenton method

Electro-Fenton method

ultraviolet catalytic oxidant method

ultrasonic oxidation method and other compound methods are introduced. Finally

the application progress and limitations of the above methods in wastewater treatment

soil remediation

landfill leachate treatment

heavy metal complex treatment and ultra-precision processing of optical materials are reviewed.

关键词

Keywords

references

XIAO H Q, LI Y Z. Research advance on quantitative detection technology of hydroxyl radical [J]. Food and Drug, 2010, 12(1): 69-71.

BAI R, LI Q L, LI J Q, et al . Research and application of Fenton and Fenton-like process in wastewater treatment [J ] . Science Technology in Chemical Industry, 2010, 18(6): 69-73.

ZHAO C S, ZHANG J K. Research progress and application on Fenton oxidation technology in wastewater treatment [J]. Environmental Science and Management, 2014, 39(5): 83-87.

CHANG W G, ZHANG S Y. The generation of hydroxyl radical in advanced oxidation processes [J]. Journal of Anqing Teachers College (Natural Science), 2004, 10(4): 24-26.

JIANG C C, XIAO R R, YANG P. Research process of advanced oxidation processes in wastewater treatment [J]. Technology of Water Treatment, 2011, 37(7): 12-16, 33.

王磊. 基于芬顿反应的单晶SiC化学机械抛光液研究[D]. 广州: 广东工业大学, 2015.

BABUPONNUSAMI A, MUTHUKUMAR K. A review on Fenton and improvements to the Fenton process for wastewater treatment [J]. Journal of Environmental Chemical Engineering, 2014, 2(1): 557-572.

WANG N N, ZHENG T, ZHANG G, et al . A review on Fenton-like processes for organic wastewater treatment [J ] . Journal of Environmental Chemical Engineering, 2016, 4(1): 762-787.

ALOK D B, WONYONG C. Review of iron-free Fenton-like systems for activatin H 2 O 2 inadvanced oxidation processes [J ] . Journal of Hazardous M aterials, 2014, 275: 121-135.

WANG L, YAN QS, LU JB, et al . Comparison of Fe catalyst species in chemical mechanical polishing based on Fenton reaction for SiC wafer [J ] . Advanced Materials Research, 2014, 1027: 171-176.

XU S P, LU J B, YAN Q S, et al . Solid catalysts based on Fenton reaction for SiC wafer in chemical mechanical polishing [J ] . Journal of Mechanical Engineering, 2017, 53(21): 167-173.

YAN Q S, XU S P, LU J B, et al . Study on chemical reaction parameters of CMP solution for single-crystal SiC [J ] . Machinery Design Manufacture, 2017(9): 98-100, 104.

ZHOU L, ZHOU M H. Review on the Electro-Fenton technology [J]. Technology of Water Treatment, 2013, 39(10): 6-11, 17.

QIU S, CHAI Y D, GU Z A, et al . Review on reaction mechanism of Electro-Fenton process [J ] . Environmental Science and Management, 2014, 39(9): 55-58.

BAN F C, DAI M Y. Research status and progress of Electro-Fenton technology [J]. Construction and Budget, 2016(11): 38-41.

NIDHEESH P V, GANDHIMATHI R. Trends in Electro-Fenton process for water and wastewater treatment: An overview [J]. Desalination, 2012, 299: 1-15.

SHAO T Y, LI X B, ZHANG B F, et al . Removal of Ni-EDTA by Electro-Fenton process [J ] . Acta Scientiae Circumstantiae, 2015, 35(3): 745-749.

SHI Y, WANG Q S, YUE L, et al . Treatment of landfill leachate by three-dimensional-electrode Electro-Fenton process [J ] . Journal of Tianjin University, 2009, 42(3): 248-252.

ZHANG P Y, YU G, JIANG Z P. Review of semiconductor photocatalyst and its modification [J]. Advances in Environmental Science, 1997, 5(3): 1-10.

ZHAO Y, ZHOU N, XIE Z W, et al . Application of UV-photocatalytic oxidation in environmental water analysis [J ] . Chemistry, 2005, 68(11): 856-862.

ZHONG L, CHEN J J. Technical progress in organic effluent water treatment by advanced oxidation processes [J]. Industrial Water Treatment, 2002, 22(1): 1-5.

LIU C F. Progress on ozonation technology of waste water treatment [J]. Petrochemical Technology Application, 2002, 20(4): 278-280.

YUAN Z W, DU H Y, HE Y, et al . Preparation of slurry for photocatalytic assisted chemical mechanical polishing CVD diamond [J ] . Diamond Abrasives Engineering, 2016, 36(5): 15-20, 31.

RUPPERT G, BAUER R, HEISLER G. The photo-Fenton reaction-an effective photochemical wastewater treatment process [J]. Journal of Photochemistry and Photobiology A: Chemistry, 1993, 73(1): 75-78.

LI L B, YU Z L. Research situation on treatment of industrial wastewater by ultrasonic oxidation [J]. Hydrometallurgy of China, 2017, 36(5): 360-364.

AHARON G. Using sonochemistry for the fabrication of nanomaterials [J]. Ultrasonics Sonochemistry, 2004, 11(2): 47-55.

SHI H X. Study on the mechanism of sonochemical reaction [J]. Chemical World, 2006, 47(10): 635-638.

PAN Y X, ZHENG H L, LI D D, et al . Degradation of organics in landfill leachate by ultrasound/Fenton process [J ] . Chinese Journal of EnvironmentalEngineering, 2008, 2(4): 445-449.

TAO C Y, LIU Z H, LI X H, et al . Study on ultrasound-assisted decolorization of methyl orange with Fenton reagent [J ] . Environmental Science, 2005, 26(5): 111-114.

FLOX C, AMMAR S, ARIAS C, et al . Electro-Fenton and photoelectro-Fenton degradation of indigo carmine in acidic aqueous medium [J ] . Applied Catalysis B: Environmental, 2006, 67(1-2): 93-104.

ELSHAFEI G M, YEHIA F, DIMITRY O, et al . Ultrasonic assisted-Fenton-like degradation of nitrobenzene at neutral pH using nanosized oxides of Fe and Cu [J ] . Ultrasonics Sonochemistry, 2014, 21(4): 1358-1365.

SHI J. Discussion on the composition of urban sewage [J]. Inner Mongolia Environmental Sciences, 2018, 30(1): 53-54.

ZENG X, ZENG D F. Study on advanced treatment of dyeing wastewater by Fenton oxidation [J]. Guangzhou Chemical Industry, 2018, 46(1): 92-94, 149.

LUO J P, HAN F, JIANG Q, et al . Pretreatment of chemical integrated wastewater by Fenton-flocculation process [J ] . Industrial Water Wastewater, 2011, 42(5): 15-19.

LIU J Y, WANG X J. Advanced treatment of fine-chemicals wastewater by Fenton reagent [J]. Environmental Science Technology, 2009, 32(5): 141-143.

DU J S, CHE D, XU Y P, et al . Study of disposing methylene blue dye wastewater by Electro-Fenton [J ] . Heilongjiang Electric Power, 2010, 32(1): 9-12.

WU Y, SUN Y W, WANG D, et al . Enhanced treatment of petrochemical reverse osmosis concentrate by an Electro- Fenton process with dosing H 2 O 2 and aeration [J ] . Chemical Industry and Engineering Progress, 2017, 36(9): 3523-3530.

SUN J F, WANG Z H, LIU J Z, et al . Study on degradation of formaldehyde by UV/O 3 [J ] . Chinese Journal of Environmental Engineering, 2009, 3(3): 506-510.

LU J X, ZHANG P Y, HE W J. Research on degradation of formaldehyde in aqueous solutionby combined photocatalysis and ozonation [J]. Chinese Journal of Environmental Engineering, 2010, 4(1): 27-30.

TANG Y B, LYU X W, CHEN F Y, et al . Study on pretreatment of coking wastewater by US/Fenton oxidation and coagulation [J ] . Industrial WaterTreatment, 2006, 26(6): 17-20.

LI J, CAO X T, SUI H, et al . Overview of remediation technologies for petroleum-contaminated soils [J ] . Acta Petrolei Sinica(Petroleum Processing Section), 2017, 33(5): 811-833.

OJINNAKA C, OSUJI L, OZIOMA A. Remediation of hydrocarbons in crude oil-contaminated soils using Fenton’s reagent [J]. Environmental Monitoring and Assessment, 2012, 184(11): 6527-6540.

徐文迪. PAHs污染土壤的电芬顿-生物泥浆反应器的联合修复[D]. 北京: 中国科学院大学, 2015.

AI J Y, ZHANG D Y, MOU S Y, et al . Removal of petroleum from soil in Qaramay usingultrasound / ultraviolet-Fenton reaction [J ] . Chinese Journal of Environmental Engineering, 2012, 6(3): 983-988.

PAN Y X, ZHENG H L, LI D D, et al . Study on landfill leachate treatment by flocculation processes [J ] . Chinese Journal of Environmental Engineering, 2007, 1(7): 97-100.

WU W J, SUN Y B, FENG J W, et al . Study on the treatment of metaphase landfill leachate [J ] . Techniques and Equipment for Environmental Pollution Control, 2006, 7(2): 112-115.

李莉. 生活垃圾填埋场渗滤液物化和生化预处理及组合处理工艺研究[D]. 重庆: 重庆大学, 2010.

吕荣谋. 垃圾渗滤液芬顿化学氧化处理工艺分析[J]. 化学工程与装备, 2017, 2016(6): 315-317.

ZHU F, OU W B, CHENG C, et al . Degradation study of landfill leachate COD removal bysacrificial anode Electro-Fenton method [J ] . Environmental Chemistry, 2013, 32(10): 1937-1942.

WANG C X, XIAO S H, ZHAO X, et al . Study on the treatment of landfill leachate by photo-Electro-Fenton oxidation [J ] . Chinese Journal of Environmental Engineering, 2009, 3(1): 11-16.

XIE L P, FU F L, TANG B. Research progress in the treatment of complex heavy metal wastewater [J]. Industrial Water Treatment, 2012, 32(8): 1-4, 40.

CHARERNTANYARAK L. Heavy metals removal by chemical coagulation and precipitation [J]. Water Science and Technology, 1999, 39(10-11): 135-138.

FU F L, WANG Q, TANG B. Fenton and Fenton-like reaction followed by hydroxide precipitation in theremoval of Ni(II) from NiEDTA wastewater: A comparative study [J]. Chemical Engineering Journal, 2009, 155(3): 769-774.

邵天元. 电/光电芬顿法处理水中络合态Ni-EDTA的研究[D]. 郑州: 华北水利水电大学, 2015.

祝敬坚. 非均相UV-Fenton体系处理金属络合染料的研究[D]. 南昌: 南昌大学, 2011.

KUBOTA A, YAGI K, MURATA J, et al . A Study on a surface preparation method for single-crystal SiC using an Fe catalyst [J ] . Journal of Electronic Materials, 2009, 38(1): 159-163.

马磊. 碳化硅光学材料芬顿辅助抛光机理与工艺研究[D]. 长沙: 国防科学技术大学, 2012.

MA L, PENG X Q, DAI Y F. Effect of Fenton-kind process in silicon carbon polishing [J]. Aviation Precision Manufacturing Technology, 2012, 48(4): 9-11, 62.

陈润. 基于芬顿反应的单晶SiC化学机械抛光加工研究[D]. 广州: 广东工业大学, 2017.

LU J B, CHEN R, LIANG H Z, et al . The influence of concentration of hydroxyl radical on the chemical mechanical polishing of SiCwafer based on the Fenton reaction [J ] . Precision Engineering, 2018, 52: 221-226.

YE Z F, ZHOU Y, XU L, et al . Chemical mechanical polishing of 4H-SiC wafer with UV-LED light [J ] . Nanotechnology and Precision Engineering, 2017, 15(5): 342-346.

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