吴伟. Treatment Process of Industrial Wastewater Containing Fluorine and Phosphor[J]. 2011, (2): 40-43.DOI:
探讨含磷含氟废水的处理工艺路线
摘要
对含磷含氟工业废水的处理工艺进行研究
并得出含磷含氟废水的处理工艺路线。含磷含氟废水的pH值<3
是典型的强酸性废水
通过石灰进行中和沉淀处理
石灰投加过程中分阶段控制pH值为11.5~8.0
并加入过量的电解质CaCl2
使生成的F-和PO4分别沉淀
沉淀后的废水用HCl调整pH值在6.0~9.0。由于沉淀分离3+过程中反应较为缓慢
对于污水管道中的沉淀物结垢问题
在清水池中设置压力水泵
定期冲洗管道;废水中部分不能完全沉淀的悬浮物
采用陶粒过滤器过滤后再排放。探讨含磷含氟废水处理工艺路线
能给予实际工程一定的指导作用。
Abstract
The treatment of the industrial wastewater containing fluorine and phosphor was examined
and the process was advanced.The pH value of the contaminated water containing fluorine and phosphor is below 3
and it is the typical acid wastewater.The lime neutralization process was showed.Firstly
a mixture of lime was used to increase the pH of the polluted water to 11.5 ~8.0.Secondly
a predetermined excess amount of calcium chloride was added to precipitate only the fluorine ion and phosphate ion.Thirdly
the hydrochloric acid was use to decrease the pH of the polluted water to 6.0~9.0.Because the process of the lime neutralization was very slow
the high pressure water was used to flush the pipes to get rid of the incrustation.Then the ceramic particle filter was used to remove the fluoride completely.The treatment process of the industrial wastewater containing fluorine and phosphor was discussed which can be a guideline for practical engineering.