EN钛硅分子筛TS-1合成工艺研究进展
钛硅分子筛TS-1合成工艺研究进展
- 中外能源 2025年30卷第3期 页码：60-69
- 作者机构：
1. 天津工业大学化学工程与技术学院
2. 中国石化催化剂有限公司工程技术研究院
3. 中国石化催化剂有限公司
- 作者简介：
- 基金信息：
DOI：
中图分类号： Q426-
纸质出版：2025
- 稿件说明：
移动端阅览
牛永超, 史建公, 苏海霞, 等. 钛硅分子筛TS-1合成工艺研究进展[J]. 中外能源, 2025,30(3):60-69.
牛永超, 史建公, 苏海霞, et al. 钛硅分子筛TS-1合成工艺研究进展[J]. 2025, 30(3): 60-69.
摘要
响应绿色化学号召，寻找更绿色、更安全、更环保的材料技术是化学领域的重点之一。减少污染物的产生和使用可再生原料、对环境无害的试剂和催化剂是实现可持续发展的重要战略。杂原子沸石因其独特的性质在工业催化中广泛应用。钛硅酸盐沸石作为最具代表性的杂原子沸石之一，在烯烃环氧化、苯酚羟基化等有机底物的H2O2选择性氧化中得到广泛的应用。近年来钛硅分子筛的合成工艺研究取得了一定进展，包括采用无机硅源和无机铝源为原料的低成本原料法、对分子筛进行深度处理的后处理法、通过合成一个固态的凝胶前驱体(通常是二氧化硅或铝硅酸盐)减少溶剂使用的干凝胶法、基于独特的加热体系促使晶核快速萌发的微波辅助法、无污染合成过程简单的无溶剂法和快速结晶及减少模板剂使用的晶种法等。这些方法旨在原料、新合成工艺以及后处理等方面对TS-1的合成进行改进。考虑到TS-1在工业应用中的重要性，持续研究低成本、低污染和高性能的合成策略至关重要。
Abstract
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references
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