为了研究钙基同步脱硫脱硝剂的性能,制备了一种钙基同步脱硫脱硝剂,采用钙基同步脱硫脱硝实验室装置,研究了SO2脱除效率、NO脱除效率及不同SO2组分下同步脱硫脱硝效率。将实验室装置放大设计,建成燃气锅炉烟气钙基同步脱硫脱硝工业装置,进行了工业连续运行试验。结果表明,气体中不含NO时,进口SO2质量浓度为995~999 mg/m3
出口降至17~21 mg/m3
满足超低排放要求,脱硫效率达到97.9%~98.3%;气体中不含SO2时,进口NO质量浓度为148~150 mg/m3
出口降至33~37 mg/m3
满足超低排放要求,脱硝效率达到75.0%~77.6%;进口NO质量浓度为150 mg/m3左右,SO2质量浓度约1000 mg/m3
脱硫效率约下降一半,脱硝效率基本不变,NO对SO2的脱除存在高浓度抑制现象;燃气锅炉烟气钙基同步脱硫脱硝工业装置连续运行4000 h
出口NO质量浓度已接近超低排放限值,钙基同步脱硫脱硝剂已达寿命周期。
In order to study the performance of calcium-based synchronous desulfurization and denitrification agent
it prepares a calcium-based synchronous desulfurization and denitrification agent
and studies the SO2 removal efficiency
NO removal efficiency and synchronous desulfurization and denitrification efficiency with different SO2 components.It enlarges and designs the laboratory device
and builts the industrial device of calcium-based synchronous desulfurization and denitrification of gas-fired boiler flue gas
and carries out the industrial continuous operation test.The results show that NO is not contained in the gas
the SO2 concentration at the inlet is 995~999 mg/m3
and the SO2 concentration at the outlet is reduced to 17~21 mg/m3
which meets the ultra-low emission requirements and the desulfurization efficiency reaches 97.9%~98.3%.When SO2 is not contained in the gas
the mass concentration of NO at the inlet is 148~150 mg/m3
the outlet is reduced to 33~37 mg/m3
which meets the requirement of ultra-low emission
and the denitration efficiency reaches 75.0%~77.6%.When the mass concentration of NO at the inlet is about 150 mg/m3 and the mass concentration of SO2 is about 1000 mg/m3
the desulfurization efficiency is reduced by about half
and the denitrification efficiency is basically unchanged
and the phenomenon of high concentration inhibition exists in the removal of SO2 by NO.The industrial device of calcium based synchronous desulfurization and denitrification of gas-fired boiler flue gas runs continuously for 4000 h
and the mass concentration of NO at the outlet is close to the ultra-low emission limit
and the calcium-based synchronous desulfurization and denitrification agent reach its life cycle.
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