CuO/TiO<sub>2</sub>催化氧化CO性能及其反应动力学

高琪; 董长青; 胡笑颖; 张俊姣; 朱雁军; 吕海洋; 薛俊杰; 王孝强

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CuO/TiO₂催化氧化CO性能及其反应动力学

更新时间：2025-10-19

- CuO/TiO₂催化氧化CO性能及其反应动力学
- 暂无标题
- 华北电力大学学报（自然科学版） 2025年第1期页码：135-142
- 作者机构：
  
  1. 1.生物质发电成套设备国家工程实验室(华北电力大学)
  2. 2.新能源电力系统全国重点实验室(华北电力大学)
  3. 3.华北电力大学能源动力与机械工程学院
  4. 4.国能生物发电集团有限公司
- 作者简介：
- 基金信息：
  
  国家自然科学基金资助项目(51776070);国家电网有限公司科技资助项目(SGGNSW00YWJS2100024)
- DOI：
  中图分类号： X701;O643.36
- 纸质出版：2025
- 稿件说明：
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高琪, 董长青, 胡笑颖, 等. CuO/TiO₂催化氧化CO性能及其反应动力学[J]. 华北电力大学学报（自然科学版）, 2025,(1):135-142.
高琪, 董长青, 胡笑颖, 等. CuO/TiO₂催化氧化CO性能及其反应动力学[J]. 华北电力大学学报（自然科学版）, 2025,(1):135-142. DOI：

DOI：

摘要

采用等体积浸渍法制备负载型CuO/TiO

催化剂，研究CuO含量、体积空速、O

含量、CO进口浓度及烟气含SO

时对催化剂CO氧化性能的影响，并对催化剂进行结构表征。结果表明：30wt%CuO/TiO

催化剂的CO催化氧化效率最佳，在10 000 h

-1

空速下180℃以上完全催化氧化CO

针对0.1～0.5vol%CO进口浓度在220～420℃实现95%以上CO转化效率。当烟气中通入SO

时，随着SO

浓度由0增至4 000 mg/m

30wt%CuO/TiO

催化剂在的CO转化率逐渐降低，SO

的存在抑制催化剂的活性。在150～180℃温度范围内进行30wt%CuO/TiO

催化剂的CO催化氧化本征反应动力学研究，实验及计算结果显示：30wt%CuO/TiO

催化剂表面的CO催化氧化可近似为一级反应，反应活化能为24.23 kJ/mol。

Abstract

关键词

Keywords

references

韩建伟,孙梓淇,佟瑶.煤粉炉低氮燃烧调整影响因素分析[J].电站系统工程,2021(03).

闫东杰,玉亚,黄学敏,刘树军,刘颖慧.SO_2对Mn-Ce/TiO_2低温SCR催化剂的毒化作用研究[J].燃料化学学报,2016(02).

范芸珠,曹发海.硫酸铵热分解反应动力学研究[J].高校化学工程学报,2011(02).

张会平,彭冠兰,鄢瑛,关建郁,肖新颜.CO在Cu-Mn催化剂上的催化氧化本征反应动力学[J].华南理工大学学报(自然科学版),2009(06).

赵迎宪,危凤,张艳辉,虞影.NO在Pt/γ-Al_2O_3上催化氧化反应机理和动力学[J].化工学报,2008(05).

于明金,解海龙,樊睿源,韩建春.燃煤电站锅炉低NO_x燃烧技术初探[J].电站系统工程,2006(02).

张会平,叶李艺.CO在铜铬银浸渍炭上催化氧化的本征反应动力学[J].厦门大学学报(自然科学版),2002(01).

Sunil Kumar,Hiya Dhar,Vijay V. Nair,Rena,Janki Govani,Shashi Arya,J.K. Bhattacharya,A.N. Vaidya,A.B. Akolkar.Environmental quality monitoring and impact assessment of solid waste dumpsites in high altitude sub-tropical regions[J].Journal of Environmental Management,2019.

Kenji Taira,Hisahiro Einaga.The Effect of SO2 and H2O on the Interaction Between Pt and TiO2(P-25) During Catalytic CO Oxidation[J].Catalysis Letters,2019.

Shim Jae-Oh,Hong Young Jun,Na Hyun-Suk,Jang Won-Jun,Kang Yun Chan,Roh Hyun-Seog.Highly Active and Stable Pt-Loaded Ce0.75Zr0.25O2 Yolk-Shell Catalyst for Water-Gas Shift Reaction.[J].ACS applied materials & interfaces,2016.

Howarth Ashlee J,Wang Timothy C,Al-Juaid Salih S,Aziz Saadullah G,Hupp Joseph T,Farha Omar K.Efficient extraction of sulfate from water using a Zr-metal-organic framework.[J].Dalton transactions (Cambridge, England : 2003),2016.

Banerjee, Sourav,Narasimhaiah, Gowrav Munithimhaiah,Mukhopadhyay, Anish,Bhattacharya, Atanu.CO Activation Determines Ultrafast Dynamics of CO Oxidation Reaction on Pd Nanoparticles[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2016.

Yeon-Su Kim,Sun Ju Lim,Young Hun Kim,Jin Ha Lee,Ho-In Lee.The role of doped Fe on the activity of alumina-supported Pt and Pd diesel exhaust catalysts[J].Research on Chemical Intermediates,2012.

Dr. Sébastien Royer,Dr. Daniel Duprez.Catalytic Oxidation of Carbon Monoxide over Transition Metal Oxides[J].ChemCatChem,2011.

Mechanism of CO oxidation over CuO/CeO_2 catalysts[J].International journal of hydrogen energy,2010.

Ruiben Jin,Yue Liu,Zhongbiao Wu,Haiqiang Wang,Tingting Gu.Low-temperature selective catalytic reduction of NO with NH 3 over Mn<ce:glyph name="sbnd"/>Ce oxides supported on TiO 2 and Al 2 O 3 : A comparative study[J].Chemosphere,2009.

Luo MF,Song YP,Lu JQ,Wang XY,Pu ZY.Identification of CuO species in high surface area CuO-CeO2 catalysts and their catalytic activities for CO oxidation[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007.

Baolin Zhu,Qi Guo,Xueliang Huang,Shurong Wang,Shoumin Zhang,Shihua Wu,Weiping Huang.Characterization and catalytic performance of TiO 2 nanotubes-supported gold and copper particles[J].Journal of Molecular Catalysis. A, Chemical,2006.

Baolin Zhu,Xiaoxiang Zhang,Shurong Wang,Shoumin Zhang,Shihua Wu,Weiping Huang.Synthesis and catalytic performance of TiO 2 nanotubes-supported copper oxide for low-temperature CO oxidation[J].Microporous and Mesoporous Materials,2006.

Remediakis Ioannis N,Lopez Nuria,Nørskov Jens K.CO oxidation on rutile-supported au nanoparticles.[J].Angewandte Chemie (International ed. in English),2005.

Rui Lin,Meng-Fei Luo,Yi-Jun Zhong,Zong-Lan Yan,Guang-Yu Liu,Wei-Ping Liu.Comparative study of CuO/Ce 0.7 Sn 0.3 O 2 , CuO/CeO 2 and CuO/SnO 2 catalysts for low-temperature CO oxidation[J].Applied Catalysis A, General,2003.

Subodh S Deshmukh,Minghui Zhang,Vladimir I Kovalchuk,Julie L d’Itri.Effect of SO 2 on CO and C 3 H 6 oxidation over CeO 2 and Ce 0.75 Zr 0.25 O 2[J].Applied Catalysis B, Environmental,2003.

Gong-Xin Qi,Jin-Hua Fei,Xiao-Ming Zheng,Zhao-Yin Hou.DME synthesis from carbon dioxide and hydrogen over Cu–Mo/HZSM-5[J].Catalysis Letters,2001.

Markus M Schubert,Stefan Hackenberg,Andre C van Veen,Martin Muhler,Vojtech Plzak,R.Jürgen Behm.CO Oxidation over Supported Gold Catalysts—“Inert” and “Active” Support Materials and Their Role for the Oxygen Supply during Reaction[J].Journal of Catalysis,2001.

Guido Busca,Luca Lietti,Gianguido Ramis,Francesco Berti.Chemical and mechanistic aspects of the selective catalytic reduction of NO x by ammonia over oxide catalysts: A review[J].Applied Catalysis B, Environmental,1998(1).

Chen,Yang.Selective Catalytic Reduction of NO with NH3 on SOa??24/TiO2 Superacid Catalyst[J].Journal of Catalysis,1993(1).

Saur O.,Bensitel M.,Saad A.B.Mohammed,Lavalley J.C.,Tripp Carl P.,Morrow B.A..The structure and stability of sulfated alumina and titania[J].Journal of Catalysis,1986(1).

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CuO/TiO2催化氧化CO性能及其反应动力学

暂无标题

DOI：

摘要

Abstract

关键词

Keywords

references

CuO/TiO₂催化氧化CO性能及其反应动力学