PAN Chunpeng, CHEN Chong, HUANG Qunxing, et al. EXPERIMENTAL STUDY ON INFLUENCE OF CaO ADDITION ON TAR GENERATION DURING BIOMASS PYRALYSIS[J]. Thermal power generation, 2012, 41(8): 18-23.
PAN Chunpeng, CHEN Chong, HUANG Qunxing, et al. EXPERIMENTAL STUDY ON INFLUENCE OF CaO ADDITION ON TAR GENERATION DURING BIOMASS PYRALYSIS[J]. Thermal power generation, 2012, 41(8): 18-23.DOI:
添加CaO对生物质热解焦油生成的影响研究
摘要
采用TG-FTIR联用技术
研究了CaO/物料(CaO/M)质量比与加热速率对竹子热解焦油生成的影响
并与干纸浆的试验结果进行对照。结果表明
焦油主要成分为酮、醛、酸、酚与烃类物质;添加CaO能显著减少焦油含量
添加比例越大其催化裂解效果越好;加热速率增大不利于减少焦油生成;800℃下竹子在管式炉热解
添加CaO极大地促进了H2的生成
而CO2与CO含量降低;随着CaO添加比例的提高
产气热值、产气率、焦炭产量随之提高;CaO/M质量比为2时相对于未添加CaO的情况下
产气热值和产气率相应提高了33.0%和27.7%。
Abstract
Based on TG-FTIR combined technology
influence of different CaO/M(material) ratios and heating rates on tar generation during pyrolysis of bamboo and dry pulp was investigated.Results show that
the tar is mainly composed of ketone
aldehyde
acid
phenol and hydrocarbon;adding CaO can dramatically reduce the tar content
and the more addition proportion
the better catalytic cracking of tar;increasing the heating rate has bad effect on reducing the tar generation.The pyrolysis of bamboo in tube furnace at 800 ℃ indicate that
the CaO additive can extremely promote the formation of H2
but the CO2 and CO content decreases;the calorific value of produced gas
gas production rate and the char yield increase with the CaO proportion increasing;compared to condition that no CaO is added
the calorific value of produced gas and gas production rate is improved by 33.0% and 27.7% respectively