LIN Tianming, ZHOU Zuoming, JING Guohua College of Chemical Engineering. Kinetics study on chelate absorption coupled with two-stage bio-reduction by immobilized microorganisms in NOx removal[J]. Thermal power generation, 2013, 42(8): 49-54.
LIN Tianming, ZHOU Zuoming, JING Guohua College of Chemical Engineering. Kinetics study on chelate absorption coupled with two-stage bio-reduction by immobilized microorganisms in NOx removal[J]. Thermal power generation, 2013, 42(8): 49-54.DOI:
The kinetic process of NOxremoval by employing an integrated process of metal chelate absorption coupled with two-stage bio-reduction using immobilized microorganisms was investigated.Several models were developed such as the bio-reduction of Fe(Ⅱ)EDTA-NO and Fe(Ⅲ)EDTA in immobilized microorganisms reactor and diffusion-reaction in immobilized beads.The results indicated that the maximum reaction rate of Fe(Ⅱ)EDTA-NO reduction by immobilized bacteria in bio-reactor was 6.97×10-6 mmol/(m3.s-1)and the half-saturation constant was 0.001 6mmol/m3.The maximum reaction rate of Fe(Ⅲ)EDTA reduction by immobilized bacteria in bio-reactor was 6.805×10-5 mmol/(m3.s-1)and the half-saturation constant was 0.013 73 mmol/m3.Furthermore
the bioreduction of Fe(Ⅱ)EDTA-NO and Fe(Ⅲ)EDTA were both controlled by interior diffusion.