HUI Shi'en, LIANG Ling, FAN Qingwei, et al. Experimental study and kinetics analysis on pyrolysis characteristics of corn stalk[J]. Thermal power generation, 2014, 43(4): 69-75.
HUI Shi'en, LIANG Ling, FAN Qingwei, et al. Experimental study and kinetics analysis on pyrolysis characteristics of corn stalk[J]. Thermal power generation, 2014, 43(4): 69-75.DOI:
To study the pyrolysis characteristics of corn stalk and determine the reaction kinetic parameters
experiments were conducted on a thermogravimetric analyzer at four heating rates of 20℃/min
40℃/min
80℃/min and 100 ℃/min
respectively.Three methods of Popescu
FWO and KAS were applied to obtain the most probable mechanism function
activation energy and preexponential factor.The kinetic analysis shows that the anti-Jander equation is the best most probable mechanism function and the activation energy has an increasing trend with the heating rate. The experimental results show that
TG curves of the corn stalk move to high temperature zone with the increasing heating rate
meanwhile
the initial and final temperature of the pyrolysis process and the peak temperature of weightlessness also increases.