ZHU Xiangyu, SUN Baomin, XIAO Haiping, et al. The role of C2H4 in plasma-assisted NOx reduction over Ag/Al2O3 catalyst[J]. Thermal power generation, 2014, 43(7): 115-118.
ZHU Xiangyu, SUN Baomin, XIAO Haiping, et al. The role of C2H4 in plasma-assisted NOx reduction over Ag/Al2O3 catalyst[J]. Thermal power generation, 2014, 43(7): 115-118.DOI:
C2H4对介质阻挡放电协同Ag/Al2O3脱除NOx的影响及机理分析
摘要
在模拟实验系统上
利用介质阻挡放电(DBD)结合Ag/Al2O3催化剂进行烟气脱硝实验
分析了C2H4对脱除NOx的影响及脱除机理。结果表明:同样情况下
添加C2H4后
NO脱除率明显升高
并且随着C2H4浓度的升高而增加;同时
加载催化剂比未加载催化剂的NO脱除率高。在能量输入密度300J/L、C2H4体积分数1%时
DBD协同Ag/Al2O3催化
NO脱除率达61.3%。分析认为:在DBD发生器中
C2H4与O2反应生成CH3O2·、HO2等强氧化性基团
将NO氧化成NO2;在催化装置中
C2H4与O2在Ag/Al2O3表面发生反应
产生更多的CH2=CH-O·和CH3COO·等自由基
最终使NOx脱除率升高。
Abstract
An experimental simulation system was built for removal of NOx from flue gas using combined method of dielectric barrier discharge(DBD)and Ag/Al2O3 catalyst.The effect of ethylene addition on NOx reduction was investigated in detail.The results show that NO removal rate increased significantly with the addition of C2H4;as the C2H4 concentration increased
the effects were enhanced.Compared to the system without catalyst
NO removal rate increased by a certain degree with catalyst.When the energy density was 300J/L and the volume fraction of ethylene was 1%
NO removal rate would reach 61.3% by DBD-Ag/Al2O3.The mechanism analysis indicates that
strong oxidizing radicals produced in DBD generator
like CH3O2·
HO2
etc.
and CH2=CH-O·
CH3COO·
etc.produced in catalytic reactor through the reaction of C2H4 with O2