ZHANG Xiaogang, WU Zhongquan, LI Shuangpei, et al. Ion exchange method based regeneration of used amine liquid from flue gas decarbonization in coal-fired power plants[J]. Thermal power generation, 2016, 45(1): 87-92.
ZHANG Xiaogang, WU Zhongquan, LI Shuangpei, et al. Ion exchange method based regeneration of used amine liquid from flue gas decarbonization in coal-fired power plants[J]. Thermal power generation, 2016, 45(1): 87-92.DOI:
The accumulation of heat stable salts(HSS)in amine liquid during CO2 capture cycle will lead to an increase in amine liquid consumption and a decrease in CO2 capture efficiency
it also causes serious corrosions.Thus
a combined process was developed
including removal of HSS anion by anion exchange resin.The resin with the optimal performances was selected through static absorption and static mechanical property tests for eight types of macroporous resins.Moreover
by dynamic absorbing tests
the best conditions for anion exchange resin absorbing and desorbing heat stable salts in organic amine liquid used for flue gas decarbonization were ascertained.For the chosen No.6resin
the most appropriate adsorption and desorption conditions are:amine liquid's flow rate of 1.5BV/h
inlet sample volume of 2BV
using NaOH solution with mass fraction of 5.0%
dosage of 3BVand flow rate of 1.5BV/h as the regeneration agent for desorption.The results show this method can regenerate the deteriorated amine liquid and the removal rate of the HSS can reach up to 95%.