HE Xiang, LIU Jianzhong, YANG Yumeng, et al. Combustion characteristics of different coals based on TG-DSC-FTIR coupled technology[J]. Thermal power generation, 2016, 45(11): 29-35.
HE Xiang, LIU Jianzhong, YANG Yumeng, et al. Combustion characteristics of different coals based on TG-DSC-FTIR coupled technology[J]. Thermal power generation, 2016, 45(11): 29-35.DOI:
On the basis of thermogravimetric-differential scanning calorimetry-fourier transform infrared spectroscopy(TG-DSC-FTIR)coupled technology
the combustion characteristics of pulverized Ximeng lignite
Datong bitumite and Yangquan anthracite were investigated.The influence of coal rank on the combustion characteristics
reaction kinetics and gaseous products release process was discussed.The results show that
with the decreasing coal rank
the ignition temperature and burnout temperature of the coals decreased
thus their ignition characteristics got stronger.Therefore
the burnout time decreased and the TGDTG-DSC curves shifted to lower temperatures.In addition
the combustion parameters of the coals
including the combustion characteristic index S
Sw
Rw and Cb
increased and the activation energy decreased.The changes of each index indicated the ignition and combustion characteristics of Ximeng lignite are the best.With a decrease in the coal rank
the precipitation peaks of CO and CO2 shifted to lower temperatures
the width of the precipitation peaks became narrower
and the release time of gaseous products shortened.Meanwhile
the ratio of release amount of CO to CO2 decreased
indicating the burnout characteristics improved.The existence pattern of sulfur in coals plays an important role in its release characterstics.