XU Qi, ZHANG Mengzhu, WANG Baowen. Chemical looping combustion characteristics and kinetics study of anthracite with CoO oxygen carrier[J]. Thermal power generation, 2017, 46(5): 27-30.
XU Qi, ZHANG Mengzhu, WANG Baowen. Chemical looping combustion characteristics and kinetics study of anthracite with CoO oxygen carrier[J]. Thermal power generation, 2017, 46(5): 27-30.DOI:
The CoO oxygen carriers were synthesized by sol-gel combustion synthesis method
and the reaction characteristics of CoO and Yangquan anthracite(YQ) and the kinetics were investigated through TG/DTG analysis. The results show that
the ignition temperature of the reaction between YQ coal and CoO was high
the volatile release characteristic index
flammability index and combustion characteristic index were small
indicating the combustion and burnout characteristics is not very good. The kinetic analysis indicates that
the reaction between the CoO and YQ coal belongs to Coats-Redfern model
and according to this model the activation energy and pre-exponential factor of the reaction are calculated respectively with different values of n. It founds that the activation energy is large and the pre-exponential factor is small