1. 浙江工商大学环境科学与工程学院
2. 北京航空航天大学化学与环境学院
3. 浙江富春江环保热电股份有限公司
网络出版:2017-08-31,
纸质出版:2017
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吴祖良, 郑欣丹, 谢德援, 等. 介质阻挡放电协同催化萘降解[J]. 高电压技术, 2017,43(8):2660-2665.
WU Zuliang, ZHENG Xindan, XIE Deyuan, et al. Naphthalene Degradation by Dielectric Barrier Discharge Coupling Catalyst[J]. 2017, 43(8): 2660-2665.
吴祖良, 郑欣丹, 谢德援, 等. 介质阻挡放电协同催化萘降解[J]. 高电压技术, 2017,43(8):2660-2665. DOI:
WU Zuliang, ZHENG Xindan, XIE Deyuan, et al. Naphthalene Degradation by Dielectric Barrier Discharge Coupling Catalyst[J]. 2017, 43(8): 2660-2665. DOI:
为了提高萘的降解效果
提出了介质阻挡放电(DBD)和催化协同降解萘的方法
研究了填充介质对放电特性和萘降解效果的影响
深入分析了TiO
2
催化剂负载量和气体温度对萘降解的影响机理。研究结果表明:填充TiO
/硅藻土对DBD放电有一定的抑制作用
导致峰值电流有所下降;填充TiO
/硅藻土较未填充时
萘的降解率及CO
x
选择率均有明显提升
特别是CO
选择率提高将近30%;随着硅藻土上TiO
负载量的增加
CO
选择率从47.5%增加至76.5%
CO2的提高幅度达到24.2%
而CO选择率的提高幅度仅4.8%;模拟气体温度由25℃升高到100℃
虽然萘的降解率仅从83.8%增加至91.8%
但CO
选择率则从45.3%增加至87.5%
增加了近1倍。TiO
对萘的降解有明显的促进作用
这为难降解有机气体的无害化处理提供了新的依据。
To improve the naphthalene degradation
we put forward a method of dielectric barrier discharge(DBD) coupling catalyst. Moreover
we studied the effect of packed media on discharge characteristics and naphthalene degradation
and deeply analyzed the influence mechanisms of naphthalene degradation under different TiO
loads and gas temperatures. The results show that the packed TiO
/diatomite has a negative function on DBD discharge
and it can lead to the decrease of peak current. Compared with that of no packed TiO
/diatomite
the degradation rate of naphthalene and CO
selectivity of packed TiO
/diatomite improves obviously
especially the CO
selectivity incre
ases nearly by 30%. With the increase of loaded amount of TiO
on the diatomite
selectivity increases from 47.5% to 76.5%. The CO
selectivity increases by 24.2%
while the CO selectivity is only 4.8%. As the temperature of simulated gas rises from 25 o C to 100 o C
the degradation rate of naphthalene increases only from 83.8% to 91.8%. However
the CO
selectivity enhances from 45.3% to 87.5%
nearly double. TiO
has played an important role in the process of naphthalene degradation
which provides a new evidence for the harmless treatment of non-degradable organic gas.
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