ZHENG Zheyu, LI Han, ZHOU Wenjun, et al. Compatibility of Eco-friendly Insulating Medium C3F7CN and Sealing Material EPDM[J]. 2020, 46(1): 335-341.DOI:
Ethylene propylene diene monomer(EPDM) is a commonly-used sealing material in SF
6
gas-insulated equipment. If eco-friendly insulating gas C
3
F
7
CN is applied instead of SF
6
without changing the sealing material of the equipment
the compatibility of C
3
F
7
CN and EPDM should be confirmed to ensure the long-term safety and stability of the gas-insulated equipment. Therefore
the compatibility test between C
3
F
7
CN and EPDM was performed by using the thermal acceleration meth
od. After the test
the stress and strain properties of the rubber specimens were tested. The changes in solid and gas compositions were analyzed by FTIR
SEM-EDS
and GC-MS. It is found that the tensile stress and strain properties are seriously degraded
and the elongation at break is reduced to less than 50% of the initial value.The multi-layered sections and cracks appear on the surface
and the crystals of inorganic additives precipitate. The damage of the rubber seriously decreases the mechanical properties. The fluorine content on the rubber surface is significantly increased
and the characteristic peak of the fluorocarbon group appears in the infrared spectrum. The gas component contains decomposition products such as CO
2
C
3
F
6
hydrocarbons
and fluoroalkanes. Additives in this particular EPDM formulation such as CaCO
3
may be sufficiently basic enough to cause decomposition of C
3
F
7
CN
which is one of the reasons for the incompatibility between EPDM and C
3
F
7
CN. This factor should be taken into account when designing and manufacturing sealing materials for gas-insulated equipment.