CHI Qingguo, YANG Meng, ZHNAG Tiandong, et al. Study on Electrical and Mechanical Properties of Calcium Copper Titanate boron Nitride Doped EPDM Composites[J]. 2021, 47(1): 223-230.
CHI Qingguo, YANG Meng, ZHNAG Tiandong, et al. Study on Electrical and Mechanical Properties of Calcium Copper Titanate boron Nitride Doped EPDM Composites[J]. 2021, 47(1): 223-230.DOI:
钛酸铜钙-氮化硼掺杂EPDM复合介质的电学和力学性能研究
摘要
非线性电导材料的应用是解决高压直流电缆附件内部电场集中问题的一种有效方案。因此
通过掺杂钛酸铜钙(calcium copper titanate
CCTO)纳米填料对三元乙丙橡胶(ethylene-propylene-diene monomer
EPDM)进行改性
在较低的掺杂体积分数(2%CCTO)下
复合介质展现出较好的非线性电导率;当掺杂10%CCTO时
非线性系数可达到5.40。但同时发现
高掺杂含量复合介质的击穿场强劣化严重。基于此
选择具有良好绝缘及导热特性的六方氮化硼(boronnitride
BN)与CCTO共同掺杂至EPDM中
研究发现
共掺杂复合介质的击穿场强有明显改善
φ=10%CCTO/ω=9%BN/EPDM的特征击穿场强为90.1 kV/mm(φ为体积分数
ω为质量分数)
相比10%CCTO/EPDM(66.3 kV/mm)提高了35.9%
此时
共掺杂复合介质仍然表现出明显的非线性电导特征。此外
探讨了温度对复合介质非线性电导和击穿特性的影响
并对掺杂复合介质的力学性能进行测试分析
研究发现
2种无机填料的掺杂对EPDM力学性能的改善效果较为显著
随着CCTO掺杂含量增加
复合介质的拉伸强度以及断裂伸长率逐渐增加。
Abstract
The application of nonlinear conductivity materials is an effective solution to solve the problem of electric field concentration in HVDC cable accessories. In this paper
ethylene-propylene-diene monomer(EPDM) is modified by doping calcium copper titanate(CCTO) nanofiller. When the doping content is lower(2% CCTO)
the composite exhibits better nonlinear conductivity. When the CCTO volume fraction reaches 10%
the nonlinear coefficient will reach 5.40. Simultaneously
the breakdown field strength of the composites with a higher CCTO content is severely degraded. Based on this phenomenon
hexagonal boron nitride(BN) with good insulation and excellent thermal conductivity is employed to dope into EPDM matrix. The breakdown field strength of the co-doped composites is significantly improved
and the characteristic breakdown field strength when φ=10%CCTO/ω=9%BN/EPDM increases to 90.1 kV/mm(φ is volume fraction
ω is mass fraction)
which is 35.9% higher than that of 10%CCTO/EPDM composites(66.3 kV/mm)
simultaneously
the co-doped composites exhibit obvious nonlinear conductivity. In addition
this paper discusses the effect of temperature on the nonlinear conductivity and breakdown characteristics of the composites. The mechanical properties of single-doped and co-doped composites are tested and analyzed. The results show that the doping of two kinds of inorganic fillers can improve the mechanical properties of EPDM
and the tensile strength and tensile elongation of composites increase gradually with the increase of CCTO doping content.