刘孟佳, 周福升, 陈铮铮, 李建英, 闵道敏, 李盛涛, 李茜, 夏荣. 采用等温表面电位衰减法表征LDPE与HDPE内陷阱的分布特性[J]. 中国电机工程学报, 2016, 36(1): 285-291. DOI: 10.13334/j.0258-8013.pcsee.2016.01.031
引用本文: 刘孟佳, 周福升, 陈铮铮, 李建英, 闵道敏, 李盛涛, 李茜, 夏荣. 采用等温表面电位衰减法表征LDPE与HDPE内陷阱的分布特性[J]. 中国电机工程学报, 2016, 36(1): 285-291. DOI: 10.13334/j.0258-8013.pcsee.2016.01.031
LIU Mengjia, ZHOU Fusheng, CHEN Zhengzheng, LI Jianying, MIN Daomin, LI Shengtao, LI Qian, XIA Rong. Characterizing Trap Distribution in LDPE and HDPE Based on Isothermal Surface Potential Decay Measurement[J]. Proceedings of the CSEE, 2016, 36(1): 285-291. DOI: 10.13334/j.0258-8013.pcsee.2016.01.031
Citation: LIU Mengjia, ZHOU Fusheng, CHEN Zhengzheng, LI Jianying, MIN Daomin, LI Shengtao, LI Qian, XIA Rong. Characterizing Trap Distribution in LDPE and HDPE Based on Isothermal Surface Potential Decay Measurement[J]. Proceedings of the CSEE, 2016, 36(1): 285-291. DOI: 10.13334/j.0258-8013.pcsee.2016.01.031

采用等温表面电位衰减法表征LDPE与HDPE内陷阱的分布特性

Characterizing Trap Distribution in LDPE and HDPE Based on Isothermal Surface Potential Decay Measurement

  • 摘要: 空间电荷积聚对直流电缆的使用寿命和运行安全有重要影响,研究聚乙烯材料内陷阱电荷的分布特性并进一步分析其内部陷阱分布特性,对抑制聚合物材料中空间电荷积聚、提高直流电缆运行的可靠性具有重要意义。通过考虑聚合物材料内电荷的脱陷规律,提出了一个计算聚合物内陷阱分布的等温表面电位衰减(isothermal surface potential decay,ISPD)模型。通过测量低密度聚乙烯(low-density polyethylene,LDPE)和高密度聚乙烯(high-density polyethylene,HDPE)试样分别在正、负电晕放电充电条件下的表面电位衰减特性,获得其相应的陷阱分布规律,并根据2种试样不同的形态学特性进行分析。结果表明:LDPE与HDPE内陷阱主要以深陷阱为主,陷阱密度近似为1021 m-3,与其它文献报道的相一致;HDPE内电子深陷阱多于LDPE内电子深陷阱,电子浅陷阱少于LDPE内电子浅陷阱;LDPE内电子深陷阱多于空穴深陷阱,电子浅陷阱少于空穴浅陷阱。分析认为:LDPE与HDPE独特的聚集态结构,以及电子和空穴电导的差异对陷阱电荷分布产生重要影响。

     

    Abstract: Space charge accumulation plays an important role in the service life and the safe operation of DC cables. Focusing on the distribution character of trapped charges and the traps within polyethylene is of great significance to control the space charge accumulation and improve the safe reliable operation of the DC cables. In this paper, isothermal surface potential decay(ISPD) model which considered the detrapping process of charges in polymeric materials was presented. The surface potential decay properties of low-density polyethylene(LDPE) and high-density polyethylene(HDPE) films were measured under the condition of positive and negative corona charging, respectively. Combining the ISPD model, the trap distribution of LDPE and HDPE were obtained and analyzed according to their morphological characteristics. The results show that there are mainly deep trapped charges in these two materials. And the trap density is nearly 1021 m-3, which is consistent with other reported literatures. The density of shallow traps in LDPE is higher than that in HDPE, while the density of the deep traps is lower. In LDPE, the density of electron-type shallow traps is lower than hole-type shallow ones, while the electron-type deep traps is higher than that of hole-type deep ones. It is indicated that the unique aggregation structure of LDPE/HDPE and different performances ofelectron/hole conduction may have a significant role in determining the distribution of trapped charges.

     

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