仝雨航, 涂垚杰, 刘豪. NH3/CH4在MILD燃烧方式下的NOx排放特性实验研究[J]. 中国电机工程学报, 2025, 45(9): 3563-3571. DOI: 10.13334/j.0258-8013.pcsee.232422
引用本文: 仝雨航, 涂垚杰, 刘豪. NH3/CH4在MILD燃烧方式下的NOx排放特性实验研究[J]. 中国电机工程学报, 2025, 45(9): 3563-3571. DOI: 10.13334/j.0258-8013.pcsee.232422
TONG Yuhang, TU Yaojie, LIU Hao. Experimental Study of NOx Emission Characteristics in CH4/NH3 MILD Combustion[J]. Proceedings of the CSEE, 2025, 45(9): 3563-3571. DOI: 10.13334/j.0258-8013.pcsee.232422
Citation: TONG Yuhang, TU Yaojie, LIU Hao. Experimental Study of NOx Emission Characteristics in CH4/NH3 MILD Combustion[J]. Proceedings of the CSEE, 2025, 45(9): 3563-3571. DOI: 10.13334/j.0258-8013.pcsee.232422

NH3/CH4在MILD燃烧方式下的NOx排放特性实验研究

Experimental Study of NOx Emission Characteristics in CH4/NH3 MILD Combustion

  • 摘要: 氨燃料利用是能源低碳转型的重要手段,MILD (moderate & intense low oxygen dilution)燃烧技术可以有效提高氨燃料的燃烧效率并降低排放。基于自行搭建的20 kW燃烧炉开展NH3/CH4混合燃料在MILD燃烧方式下的NOx排放特性实验研究,重点考察掺氨比、当量比以及炉膛内壁面温度对NO、NO2及N2O排放的影响规律,并与常规旋流燃烧方式进行系统对比。结果表明,相较于常规燃烧,MILD燃烧可有效降低氨燃料燃烧中NO和NO2的排放,但存在N2O排放问题。NO排放在35%~40%掺氨比和0.8当量比下达到峰值,并跟随壁温线性上升。随着掺氨比的提高和壁温的降低,N2O排放逐步升高,在1 000 K壁温、55%掺氨比条件下,N2O排放高达40×10−6。因此,在氨燃料MILD燃烧中,需协调N2O排放与NO排放,尽可能降低NOx排放。

     

    Abstract: Ammonia fuel utilization is an important means of energy low-carbon transition, moderate & intense low oxygen dilution (MILD) combustion technology can effectively improve the combustion efficiency of ammonia fuel and reduce emissions. Based on a self-built 20kW combustion furnace, an experimental study is carried out on NOx emission characteristics of NH3/CH4 mixed fuel in MILD combustion mode, focusing on the influence of ammonia ratio, equivalent ratio and furnace inner wall temperature on NO, NO2 and N2O emission, and systematic comparison is made with the traditional swirl combustion mode. Studies demonstrate that compared with traditional combustion, MILD combustion can effectively reduce the emission of NO and NO2 in ammonia fuel combustion, but N2O emission occurs in MILD combustion. NO emissions peak at an ammonia ratio of 35%~40% and an equivalence ratio of 0.8, exhibiting a linear increase with wall temperature. With the increase of ammonia ratio and the decrease of wall temperature, the emission of N2O gradually increases. At 1000K wall temperature and 55% ammonia ratio, the emission of N2O reaches 40×10−6. In MILD combustion of ammonia fuel, coordinated control of N2O and NO emissions is essential for effective NOx reduction.

     

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