黄文仕, 王智雄, 林立, 伍泽赟, 王大彪, 罗宇, 陈崇启, 江莉龙. 基于氨预分解的氨扩散燃烧模拟研究[J]. 中国电机工程学报, 2025, 45(2): 479-488. DOI: 10.13334/j.0258-8013.pcsee.232238
引用本文: 黄文仕, 王智雄, 林立, 伍泽赟, 王大彪, 罗宇, 陈崇启, 江莉龙. 基于氨预分解的氨扩散燃烧模拟研究[J]. 中国电机工程学报, 2025, 45(2): 479-488. DOI: 10.13334/j.0258-8013.pcsee.232238
HUANG Wenshi, WANG Zhixiong, LIN Li, WU Zeyun, WANG Dabiao, LUO Yu, CHEN Chongqi, JIANG Lilong. Simulation on Ammonia Diffusion Combustion Based on Ammonia Pre-decomposition[J]. Proceedings of the CSEE, 2025, 45(2): 479-488. DOI: 10.13334/j.0258-8013.pcsee.232238
Citation: HUANG Wenshi, WANG Zhixiong, LIN Li, WU Zeyun, WANG Dabiao, LUO Yu, CHEN Chongqi, JIANG Lilong. Simulation on Ammonia Diffusion Combustion Based on Ammonia Pre-decomposition[J]. Proceedings of the CSEE, 2025, 45(2): 479-488. DOI: 10.13334/j.0258-8013.pcsee.232238

基于氨预分解的氨扩散燃烧模拟研究

Simulation on Ammonia Diffusion Combustion Based on Ammonia Pre-decomposition

  • 摘要: 氨部分预分解是改善氨的燃烧性能的有效手段,但对于氨预分解条件的影响仍缺乏系统的研究。该文针对基于氨预分解策略的氨扩散燃烧装置开展数值模拟研究,以分析氨预分解比例、当量比和氨分解余热对燃烧及污染物排放特性的影响。结果表明,随着氨预分解比例提高,火焰温度提高,火焰高温区更靠近喷嘴,NOx排放量下降;NO排放在NOx中占主导,并随着当量比的提高先增大后减小;N2O排放主要发生在低氨预分解比例、低当量比条件下,在氨预分解比例达到50%后基本消失;利用氨分解余热预热燃料有助于稳定燃烧,并在氨预分解比例不超过30%时,明显减少氨泄漏而未增加NOx排放。研究表明,提高氨预分解比例和当量比能有效改善氨燃烧及污染物排放特性,而在小比例氨预分解条件下应充分利用氨分解的余热。

     

    Abstract: Partial pre-decomposition of ammonia is an effective means to improve the combustion performance of ammonia. This work conducts numerical simulation on an ammonia diffusion combustion device based on ammonia pre-decomposition strategy. The effects of ammonia pre-decomposition ratio, equivalence ratio, and residual heat from ammonia pre-decomposition on combustion and pollutant emission characteristics are analyzed. As the ammonia pre-decomposition ratio increases, the flame temperature increases, the high-temperature zone of the flame moves closer to the nozzle, and the NOx emissions decrease. NO emission dominates in NOx emissions, increasing first and then decreasing as the equivalence ratio increases. N2O emission mainly occurs under low ammonia pre-decomposition ratio and low equivalence ratio conditions, and hardly exists after the ammonia pre-decomposition ratio reaches over 50%. Preheating fuel with residual heat from ammonia decomposition can stabilize combustion and significantly decrease ammonia leakage without increasing NOx emissions when the ammonia pre-decomposition ratio does not exceed 30%. This study shows that increasing the ammonia pre-decomposition ratio and equivalence ratio can effectively improve the combustion and pollutant emission characteristics of ammonia, and the residual heat from ammonia decomposition should be fully utilized under small proportion ammonia pre-decomposition conditions.

     

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