丁文杰, 张亮, 李俊, 杨扬, 黄健, 付乾, 朱恂, 廖强. 膜内掺Pt含量对质子交换膜电解水性能与氢渗透的影响[J]. 中国电机工程学报, 2024, 44(14): 5588-5595. DOI: 10.13334/j.0258-8013.pcsee.230612
引用本文: 丁文杰, 张亮, 李俊, 杨扬, 黄健, 付乾, 朱恂, 廖强. 膜内掺Pt含量对质子交换膜电解水性能与氢渗透的影响[J]. 中国电机工程学报, 2024, 44(14): 5588-5595. DOI: 10.13334/j.0258-8013.pcsee.230612
DING Wenjie, ZHANG Liang, LI Jun, YANG Yang, HUANG Jian, FU Qian, ZHU Xun, LIAO Qiang. Effect of Pt Content in Membrane on Performance and Hydrogen Permeation of Proton Exchange Membrane Water Electrolysis[J]. Proceedings of the CSEE, 2024, 44(14): 5588-5595. DOI: 10.13334/j.0258-8013.pcsee.230612
Citation: DING Wenjie, ZHANG Liang, LI Jun, YANG Yang, HUANG Jian, FU Qian, ZHU Xun, LIAO Qiang. Effect of Pt Content in Membrane on Performance and Hydrogen Permeation of Proton Exchange Membrane Water Electrolysis[J]. Proceedings of the CSEE, 2024, 44(14): 5588-5595. DOI: 10.13334/j.0258-8013.pcsee.230612

膜内掺Pt含量对质子交换膜电解水性能与氢渗透的影响

Effect of Pt Content in Membrane on Performance and Hydrogen Permeation of Proton Exchange Membrane Water Electrolysis

  • 摘要: 针对质子交换膜电解水制氢中存在的氢渗透安全隐患,该文通过超声喷涂将纳米Pt颗粒负载到膜上,并经过热压制备掺Pt复合膜,以缓解运行中的氢渗透。在保持膜电极总Pt含量不变的条件下,研究膜内不同掺Pt含量对性能与氢渗透的影响。结果表明,通过超声喷涂和热压成功将纳米Pt颗粒负载到膜中,并有效缓解了氢渗透。随着膜内掺Pt含量的增加,氢渗透通量降低,同时由于阴极Pt含量降低、欧姆损失增大,电解性能呈现逐渐降低的趋势。综合考虑氢渗透和电解性能,最佳的掺Pt含量为0.01 mg/cm2,在0.1 A/cm2时,氧中氢含量仅为0.82%,与无Pt复合膜相比,氢渗透降低了50.32%,而电解电压仅增加约20 mV。长时间运行电解电压和氧中氢浓度相对较稳定,氧中氢浓度低于氢气爆炸下限。

     

    Abstract: Aiming at the potential safety hazards of hydrogen permeation by proton exchange membrane water electrolysis, nano Pt particles are doped into the membrane by ultrasonic spraying and then Pt doped composite membrane is obtained by hot pressing to alleviate the hydrogen permeation phenomenon. Under the condition of keeping the total Pt content of membrane electrode unchanged, the effects of different Pt content in membrane on the performance and hydrogen permeation of proton exchange membrane water electrolysis are studied. The results show that nano Pt particles are successfully loaded into the membrane by ultrasonic spraying and hot pressing, thus effectively alleviating hydrogen permeation. With the increase of Pt content in the membrane, the hydrogen permeation flux decreases, but the electrolytic performance also decreases because of the gradually increasing ohmic loss. Considering the hydrogen permeation and electrolysis performance, the optimal Pt content in this paper is 0.01 mg/cm2; at 0.1 A /cm2 the hydrogen in oxygen content is only 0.82%. Compared with the membrane without Pt, the hydrogen permeation is reduced by 50.32%, and the electrolysis voltage is only increased by about 20 mV. During long-term operation, the electrolytic voltage and the hydrogen concentration in the oxygen are relatively stable and the hydrogen concentration in oxygen is below the lower limit of the explosion.

     

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