李良钰, 谭厚章, 王学斌, 阮仁晖, 马道洋, 郑仕杰, 王毅斌. 高氯煤的研究进展和应用技术现状[J]. 中国电机工程学报, 2022, 42(11): 4040-4059. DOI: 10.13334/j.0258-8013.pcsee.211278
引用本文: 李良钰, 谭厚章, 王学斌, 阮仁晖, 马道洋, 郑仕杰, 王毅斌. 高氯煤的研究进展和应用技术现状[J]. 中国电机工程学报, 2022, 42(11): 4040-4059. DOI: 10.13334/j.0258-8013.pcsee.211278
LI Liangyu, TAN Houzhang, WANG Xuebin, RUAN Renhui, MA Daoyang, ZHENG Shijie, WANG Yibin. Research Progress and Applied Technical Status of High Chlorine Coal Utilization[J]. Proceedings of the CSEE, 2022, 42(11): 4040-4059. DOI: 10.13334/j.0258-8013.pcsee.211278
Citation: LI Liangyu, TAN Houzhang, WANG Xuebin, RUAN Renhui, MA Daoyang, ZHENG Shijie, WANG Yibin. Research Progress and Applied Technical Status of High Chlorine Coal Utilization[J]. Proceedings of the CSEE, 2022, 42(11): 4040-4059. DOI: 10.13334/j.0258-8013.pcsee.211278

高氯煤的研究进展和应用技术现状

Research Progress and Applied Technical Status of High Chlorine Coal Utilization

  • 摘要: 我国新疆地区煤炭储量占全国预测煤炭储量的近40%,其中沙尔湖煤作为典型的新疆煤种之一,其储量近1000亿吨,该煤低灰、低硫、着火特性极佳,但是煤中氯含量可超过1%,如此罕见的高氯特性导致该煤在高效燃煤发电和现代煤化工中的结焦、沾污和腐蚀问题极其严重,制约了沙尔湖煤的安全、高效和清洁利用。在该技术背景下,对国内外高氯煤的研究进展和应用技术现状进行了综述,主要包括:1)世界和中国高氯煤的燃料特性、分布特性和利用技术现状;2)煤中氯的赋存形态,包括无机形态(与矿物元素结合形成离散的氯化物、含氯复杂矿物、存于孔隙水中离子形态)和有机形态(弱结合吸附形态,强结合共价形态);3)燃烧和热解过程中氯释放的影响因素和氯的迁徙形态及特性;4)高氯煤燃用过程中氯诱导的受热面沾污和腐蚀机制;5)燃烧过程中二噁英和汞等重金属与氯的耦合作用机制;6)氯的控制技术,包括炉前、炉内和炉后控制技术。基于文献调研和分析研究,为今后高氯煤领域的基础研究重点和技术研发方向提出建议。

     

    Abstract: Nearly 40% of the predicted coal reserves in China are located in Xinjiang. Shaerhu coal, which has a reserve of nearly 100 billion tons is one of the typical Xinjiang coals. It has low ash, low sulfur and excellent ignition characteristics; however, the chlorine content in Shaerhu coal can exceed 1%. Such rare high chlorine characteristic leads to extremely serious coking, contamination and corrosion problems in high-efficiency coal-fired power generation and modern coal chemical industry, which restricts the safe, efficient and clean utilization of Shaerhu coal. Under this circumstance, the research progress and applied technical status of high chlorine coal utilization technology in China and abroad were reviewed as follows: 1) fuel characteristics, distribution status and utilization technology of high chlorine coal in the world and in China; 2) chlorine occurrence in coal include inorganic forms (discrete chloride combining with mineral elements, complex minerals containing chlorine, ionic forms existing in water from pore of particles) and organic forms (weak binding adsorption forms, strong binding covalent forms); 3) during combustion and pyrolysis the influencing factors of chlorine release and the transformation and migration characteristics; 4) the mechanism of chlorine induced fouling and corrosion of heating surface in the process of high chlorine coal combustion; 5) the coupling mechanism of mercury and other heavy metals with chlorine and role of Cl in the formation of dioxin; 6) chlorine control technology, including flue gas dechlorination technology in front of furnace, in the furnace and after furnace. Based on the literature research and analysis, this paper put forward some suggestions for the basic research focus and the direction of technology development in the field of high chlorine coal in the future.

     

/

返回文章
返回