徐蒙, 张竹茜, 贾力, 杨立新. 圆柱形锂离子动力电池放电过程电化学与传热特性研究[J]. 中国电机工程学报, 2013, 33(32): 54-61,5. DOI: 10.13334/j.0258-8013.pcsee.2013.32.011
引用本文: 徐蒙, 张竹茜, 贾力, 杨立新. 圆柱形锂离子动力电池放电过程电化学与传热特性研究[J]. 中国电机工程学报, 2013, 33(32): 54-61,5. DOI: 10.13334/j.0258-8013.pcsee.2013.32.011
XU Meng, ZHANG Zhuqian, JIA Li, YANG Lixin. Study on Electrochemical and Heat Transfer Characteristics of Cylindrical Lithium-ion Power Battery During Discharge Cycle[J]. Proceedings of the CSEE, 2013, 33(32): 54-61,5. DOI: 10.13334/j.0258-8013.pcsee.2013.32.011
Citation: XU Meng, ZHANG Zhuqian, JIA Li, YANG Lixin. Study on Electrochemical and Heat Transfer Characteristics of Cylindrical Lithium-ion Power Battery During Discharge Cycle[J]. Proceedings of the CSEE, 2013, 33(32): 54-61,5. DOI: 10.13334/j.0258-8013.pcsee.2013.32.011

圆柱形锂离子动力电池放电过程电化学与传热特性研究

Study on Electrochemical and Heat Transfer Characteristics of Cylindrical Lithium-ion Power Battery During Discharge Cycle

  • 摘要: 锂离子动力电池放电过程中的内部产热对电池性能和安全运行有重要影响。该文通过对磷酸铁锂动力电池建立一个涉及质量守恒、电荷守恒和能量守恒,并伴有电化学反应过程的电化学-热耦合模型,研究电池恒流放电过程的温度场和生热速率,并通过实验验证了模型的合理性。结果表明,低倍率放电时,可逆生热速率在总生热速率中所占份额较大;而高倍率放电时,欧姆热生热速率占绝对优势。大电流放电时,产热速率高,有必要使用电池热管理系统。

     

    Abstract: The heat generation in a cell has a strong influence on performance and safe operation of Lithium-ion power battery. To study the temperature distribution and heat generation rate of a basic LiFePO4lithium ion battery at various galvanostatic discharge rates, an electro-thermal mathematical model was developed where the mass, charge,and thermal transport processes were considered, as well as the electrochemical reaction phenomena. The thermal characteristics predicted by the model agreed well with the experimental data. The results indicate that the reversible heat has a larger proportion of total heat generation under a lower discharge rate, while the ohmic heat is dominant under a higher discharge rate. A battery thermal management system is necessary under high discharge rate due to the higher temperature rise.

     

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