陈莹, 张健. 气相温度脉动对碳黑成核与长大及氧化反应的影响[J]. 中国电机工程学报, 2011, 31(14): 50-56. DOI: 10.13334/j.0258-8013.pcsee.2011.14.016
引用本文: 陈莹, 张健. 气相温度脉动对碳黑成核与长大及氧化反应的影响[J]. 中国电机工程学报, 2011, 31(14): 50-56. DOI: 10.13334/j.0258-8013.pcsee.2011.14.016
CHEN Ying, ZHANG Jian. Effects of Gas Temperature Fluctuations on the Soot Inception,Growth,and Oxidation Reactions[J]. Proceedings of the CSEE, 2011, 31(14): 50-56. DOI: 10.13334/j.0258-8013.pcsee.2011.14.016
Citation: CHEN Ying, ZHANG Jian. Effects of Gas Temperature Fluctuations on the Soot Inception,Growth,and Oxidation Reactions[J]. Proceedings of the CSEE, 2011, 31(14): 50-56. DOI: 10.13334/j.0258-8013.pcsee.2011.14.016

气相温度脉动对碳黑成核与长大及氧化反应的影响

Effects of Gas Temperature Fluctuations on the Soot Inception,Growth,and Oxidation Reactions

  • 摘要: 研究气相温度脉动对碳黑成核与长大反应以及碳黑氧化反应的影响。计算结果表明,在气相平均温度为1 500~1 800 K的条件下,碳黑成核和表面长大过程以及碳黑氧化过程中碳黑质量分数的瞬时变化都受到气相温度脉动的影响,这种影响随气相温度脉动强度的增加而变大。在碳黑成核和表面长大过程中,气相温度脉动加快了碳黑成核和表面长大反应的进行,温度脉动强度的增加使得碳黑时均质量分数增加。在碳黑氧化过程中,气相温度脉动强度的增加导致碳黑时均质量分数减少,而时均颗粒数密度则有所增加。

     

    Abstract: The effects of gas temperature fluctuations on the soot inception and surface growth reactions as well as soot oxidation reactions are investigated.The results indicate that the instantaneous variations of soot mass fraction are influenced by the gas temperature fluctuation in both processes of soot inception and surface growth and soot oxidation under the time-averaged gas temperature of 1 500~1 800 K.The influences are enhanced by the increase in the fluctuation amplitude of the gas temperature.The gas temperature fluctuation results in faster rates of soot nucleation and surface growth reactions in the processes of soot inception and surface growth.The time-averaged soot mass fraction increases with the fluctuation amplitude of the gas temperature.While the increase in the fluctuation amplitude of the gas temperature leads to decrease in the time-averaged soot mass fraction and increase in the time-averaged soot particle number density during the processes of soot oxidation.

     

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