Abstract: The Blockchain has the features of intelligent contracts, distribution decision, cooperative autonomy and tamper resistance. These characteristics make it naturally similar to the Energy Internet in running ways, topological form, bilateral trade and synergic dispatch and so on. It can finely support the construction of Energy Internet. Based on the analysis of the physical topological and the logical protocol hierarchy of the Energy Internet, this paper, from the perspective of Blockchain as well as Energy Internet, proposed the Energy Internet hierarchy model which based on Blockchain and designed the intelligent trade model of Energy Internet and trust mechanism. Beyond that, this paper also discussed the synergic scheduling model between vertical hierarchical scheduling system and multi-level substation after the decentralized of the dispatch section as well as the corresponding security check of power grid and physical constraints. It also formed an Energy Internet intelligent transaction and collaborative scheduling model, based on block chain technology, supporting the "horizontal multi-source complementary, vertical collaborative scheduling" system, and it is conducive to the perfect integration of energy flow and information flow and secure transmission.