陈莹, 李富强. 反溶剂对CsPbBr3太阳电池性能的影响[J]. 太阳能学报, 2024, 45(4): 122-126. DOI: 10.19912/j.0254-0096.tynxb.2023-2169
引用本文: 陈莹, 李富强. 反溶剂对CsPbBr3太阳电池性能的影响[J]. 太阳能学报, 2024, 45(4): 122-126. DOI: 10.19912/j.0254-0096.tynxb.2023-2169
Chen Ying, Li Fuqiang. EFFECT OF ANTISOLVENT ON PERFORMANCE OF CsPbBr3 SOLAR CELLS[J]. Acta Energiae Solaris Sinica, 2024, 45(4): 122-126. DOI: 10.19912/j.0254-0096.tynxb.2023-2169
Citation: Chen Ying, Li Fuqiang. EFFECT OF ANTISOLVENT ON PERFORMANCE OF CsPbBr3 SOLAR CELLS[J]. Acta Energiae Solaris Sinica, 2024, 45(4): 122-126. DOI: 10.19912/j.0254-0096.tynxb.2023-2169

反溶剂对CsPbBr3太阳电池性能的影响

EFFECT OF ANTISOLVENT ON PERFORMANCE OF CsPbBr3 SOLAR CELLS

  • 摘要: 分别在钙钛矿前驱体中添加一系列的反溶剂乙酸乙酯(EA)和乙腈(ACN),制备出不同形貌的CsPbBr3薄膜,探究薄膜质量与太阳电池性能的内在联系。结果表明,在大气制备环境中,反溶剂有助于CsPbBr3晶粒的生长,薄膜表面缺陷明显减少,太阳电池各性能参数(短路电流密度、开路电压以及填充因子)均有所提升,尤其是添加乙腈(V(PbBr2/DMF)∶V(ACN)=10∶1)后,光电转换效率(PCE)从3.16%提高到7.10%。

     

    Abstract: In this paper,a series of antisolvent ethyl acetate(EA)and acetonitrile(ACN)were added to the perovskite precursor to prepare CsPbBr3thin films with different morphologies,and the effect of thin film quality on the performance of perovskite solar cells was studied.Research results show that in the atmosphere preparation environment,the antisolvent can promote the growth of CsPbBr3grain,the surface defects of the film are significantly reduced,and the short circuit current density,open circuit voltage and filling factor of the prepared FTO/TiO2/CsPbBr3/Carbon structure solar cells are improved.In particular,when acetonitrile(V(PbBr2/DMF)∶V(ACN)is 10∶1)was added,the solar cell photoelectric conversion efficiency(PCE)was increased from 3.16%to 7.10%.

     

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