苏诗茜, 应智琴, 陈邢凯, 李鑫, 杨熹, 叶继春. 基于金刚线切片的钙钛矿/硅叠层太阳电池[J]. 太阳能学报, 2024, 45(4): 23-29. DOI: 10.19912/j.0254-0096.tynxb.2023-1438
引用本文: 苏诗茜, 应智琴, 陈邢凯, 李鑫, 杨熹, 叶继春. 基于金刚线切片的钙钛矿/硅叠层太阳电池[J]. 太阳能学报, 2024, 45(4): 23-29. DOI: 10.19912/j.0254-0096.tynxb.2023-1438
Su Shiqian, Ying Zhiqin, Chen Xingkai, Li Xin, Yang Xi, Ye Jichun. PEROVSKITE/SILICON TANDEM SOLAR CELLS BASED ON DIAMOND-WIRE SAWN[J]. Acta Energiae Solaris Sinica, 2024, 45(4): 23-29. DOI: 10.19912/j.0254-0096.tynxb.2023-1438
Citation: Su Shiqian, Ying Zhiqin, Chen Xingkai, Li Xin, Yang Xi, Ye Jichun. PEROVSKITE/SILICON TANDEM SOLAR CELLS BASED ON DIAMOND-WIRE SAWN[J]. Acta Energiae Solaris Sinica, 2024, 45(4): 23-29. DOI: 10.19912/j.0254-0096.tynxb.2023-1438

基于金刚线切片的钙钛矿/硅叠层太阳电池

PEROVSKITE/SILICON TANDEM SOLAR CELLS BASED ON DIAMOND-WIRE SAWN

  • 摘要: 提出一种免空穴传输层的策略,将自组装单分子层材料作为钙钛矿活性层的添加剂,通过一步旋涂法直接将钙钛矿薄膜制备在导电基底表面,其中薄膜的质量与均一性都得到改善。进一步地,将该方法应用在低成本的商用金刚线切片上,可在高粗糙度的硅表面制备出覆盖度高、形貌致密、无空洞的钙钛矿薄膜。在光电性能方面,用该方法得到的单结钙钛矿太阳电池的光电转换效率为21%,填充因子高达83%,两端钙钛矿/硅叠层太阳电池的光电转换效率为28%。

     

    Abstract: In this study,a strategy of hole transport layer-free(HTL-free)is proposed. The self-assembled monolayer is used as the additive of perovskite active layer,then the perovskite film is directly deposited on the conductive substrate surface using a one-step spin coating method,and the quality and uniformity of the film are improved. Furthermore,the method is applied to the commercial and low-cost diamond-wire sawn with high surface roughness,resulting in the formation of a perovekite film characterized by high coverage,dense morphoogy,and absence of cavities. In terms of the photoelectric performance,the single-junction perovskite solar cells yield a champion power conversion efficiency(PCE)of 21.3%,with a high fill factor(FF)of over 83%. Finally,a PCE of 28% for perovskite/silicon tandem solar cells based on diamond-wire sawn is demonstrated.

     

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