简雅婷, 王帆, 陈小燕, 张宇, 余强, 袁振宏. 药渣木质素定向解聚制备高密度航油合成原料[J]. 太阳能学报, 2024, 45(3): 163-168. DOI: 10.19912/j.0254-0096.tynxb.2022-1815
引用本文: 简雅婷, 王帆, 陈小燕, 张宇, 余强, 袁振宏. 药渣木质素定向解聚制备高密度航油合成原料[J]. 太阳能学报, 2024, 45(3): 163-168. DOI: 10.19912/j.0254-0096.tynxb.2022-1815
Jian Yating, Wang Fan, Chen Xiaoyan, Zhang Yu, Yu Qiang, Yuan Zhenhong. PREPARATION OF FEEDSTOCK FOR HIGH DENSITY JET FUEL SYNTHESIS BY TARGETED DEPOLYMERIZATION OF LIGNIN FROM PHARMACEUTICAL RESIDUES[J]. Acta Energiae Solaris Sinica, 2024, 45(3): 163-168. DOI: 10.19912/j.0254-0096.tynxb.2022-1815
Citation: Jian Yating, Wang Fan, Chen Xiaoyan, Zhang Yu, Yu Qiang, Yuan Zhenhong. PREPARATION OF FEEDSTOCK FOR HIGH DENSITY JET FUEL SYNTHESIS BY TARGETED DEPOLYMERIZATION OF LIGNIN FROM PHARMACEUTICAL RESIDUES[J]. Acta Energiae Solaris Sinica, 2024, 45(3): 163-168. DOI: 10.19912/j.0254-0096.tynxb.2022-1815

药渣木质素定向解聚制备高密度航油合成原料

PREPARATION OF FEEDSTOCK FOR HIGH DENSITY JET FUEL SYNTHESIS BY TARGETED DEPOLYMERIZATION OF LIGNIN FROM PHARMACEUTICAL RESIDUES

  • 摘要: 以三叉苦药渣木质素为原料,在低共熔溶剂(ChCl-MeOH-AlCl3·6H2O)与催化剂(Cu(OAc)2/邻菲罗啉)耦合作用下解聚生成高密度航油合成原料,考察不同反应温度、时间、固液比、催化剂添加量与氧气含量对木质素催化氧化解聚效果的影响。结果表明:在固液比1∶30 g/mL,木质素、Cu(OAc)2、邻菲罗啉的质量比1∶1∶1,3 MPa氧压,60℃条件下反应3 h后,木质素选择性解聚生了芳香醛酮类高密度航油合成原料,木质素转化率达到80.84%,香草乙酮与香草醛收率分别为16.69%和34.39%。

     

    Abstract: Herein,Lignin from evodia lepta was used as raw material to depolymerize under the coupling of deep eutectic solvent(ChCl-MeOH-AlCl3·6H2O)and catalyst(Cu(OAc)2/1,10-phenanthroline)to generate feedstock for synthesising high-density jet fuel,and the effects of different reaction temperatures,times,solid-liquid ratios,catalyst additions and oxygen pressures on the catalytic oxidative depolymerization of lignin were investigated. The results showed that under the conditions of solid-liquid ratio of 1∶30 g/mL,mass ratio of lignin to Cu(OAc)2 and 1,10-phenanthroline of 1∶1∶1,oxygen pressure of 3 MPa and 60 ℃ for 3 h,the lignin was selectively depolymerized to produce aromatic aldehydes and ketones used as feedstock for synthesizing high-density jet fuel. The lignin conversion rate reached 80.84%,and the yields of acetovanillone and vanillin were 16.69% and 34.39%,respectively.

     

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