程家文, 曾丽萍, 生梦瑶, 苏欢, 李文菁, 李小华. MWCNTs-水合盐复合相变材料的蓄热性能研究[J]. 太阳能学报, 2023, 44(8): 10-16. DOI: 10.19912/j.0254-0096.tynxb.2022-0556
引用本文: 程家文, 曾丽萍, 生梦瑶, 苏欢, 李文菁, 李小华. MWCNTs-水合盐复合相变材料的蓄热性能研究[J]. 太阳能学报, 2023, 44(8): 10-16. DOI: 10.19912/j.0254-0096.tynxb.2022-0556
Cheng Jiawen, Zeng Liping, Sheng Mengyao, Su Huan, Li Wenjing, Li Xiaohua. STUDY ON HEAT STORAGE PERFORMANCE OF MWCNTs-HYDRATED SALT COMPOSITE PHASE CHANGE MATERIAL[J]. Acta Energiae Solaris Sinica, 2023, 44(8): 10-16. DOI: 10.19912/j.0254-0096.tynxb.2022-0556
Citation: Cheng Jiawen, Zeng Liping, Sheng Mengyao, Su Huan, Li Wenjing, Li Xiaohua. STUDY ON HEAT STORAGE PERFORMANCE OF MWCNTs-HYDRATED SALT COMPOSITE PHASE CHANGE MATERIAL[J]. Acta Energiae Solaris Sinica, 2023, 44(8): 10-16. DOI: 10.19912/j.0254-0096.tynxb.2022-0556

MWCNTs-水合盐复合相变材料的蓄热性能研究

STUDY ON HEAT STORAGE PERFORMANCE OF MWCNTs-HYDRATED SALT COMPOSITE PHASE CHANGE MATERIAL

  • 摘要: 研究CH3COONa·3H2O(SAT)/Na2HPO4·12H2O(DSP)共晶盐的相变过程,分析亲水碳纳米管(HCNTs)对共晶盐热性能的优化效果。结果表明:SAT/DSP质量比为9∶1时共晶盐循环稳定性最好,且过冷度仅为2.5℃;随着HCNTs掺量提高,复合材料的热导率呈线性增长趋势,最高达到1.29 W/(m·K),较未加HCNTs时提升了182.89%,蓄热密度呈线性下降趋势,最多降低了5.59%。最后对各组HCNTs/SAT/DSP复合相变材料(CPCM)进行200次固-液循环,结果表明各组材料的循环稳定性良好,具备实际应用价值。

     

    Abstract: The phase change process of CH3COONa·3H2O(SAT)/Na2HPO4·12H2O(DSP)eutectic salt was studied experimentally,and the optimization effect of hydrophilic carbon nanotubes(HCNTs)on the thermal properties of eutectic salt was analyzed.The results show that the cyclic stability of eutectic salt is best when the mass ratio of SAT/DSP is 9∶1,and the degree of supercooling is only 2.5℃.As the mass fraction of the HCNTs attained is increased,the thermal conductivity of the composite shows a linear increase trend;the highest value 1.29 W/(m·K),which is 182.89%higher than that without HCNTs.Conversely,the heat storage density manifests a downward linear trend,reaching a maximum decrease of 5.59%.Furthermore,the cyclic stability of HCNTs/SAT/DSP composites was tested,with the results revealing that after 200 solid-liquid cycles,the cyclic stability of each group of materials is good,and it has practical application value.

     

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