癸酸-石蜡二元低共熔复合相变材料的制备及性能研究
PREPARATION AND PROPERTIES OF CAPRIC ACID-PARAFFIN BINARY LOW EUTECTIC COMPOSITE PHASE CHANGE MATERIALS
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摘要: 为充分利用冬季太阳辐射热,将传统建筑材料与相变材料结合形成新型绿色建筑材料,可充分发挥其储能控温特性,并缩短热量被吸收进室内的时间,降低冬季采暖能耗,实现建筑节能。利用熔融共混法制备了质量配比为0.81∶0.19、共晶温度为27.4℃的癸酸-石蜡(CA-PC)低共熔复合相变材料。通过傅里叶红外光谱仪(FT-IR)对该二元低共熔物的化学结构进行分析,发现CA与PC是通过物理作用结合的,无新物质产生;并且通过500次加速冷热循环实验,证实了CA-PC复合相变材料具有良好的热循环稳定性。此外,由差示扫描量热仪(DSC)分析得到CA-PC的相变温度为27.0℃,相变潜热为153.7 J/g,这一结果与步冷曲线所得的共晶温度相吻合,进一步表明了该复合相变材料在用于制备新型建筑储能材料领域极具发展潜力。Abstract: In order to make full use of solar radiant heat in winter,traditional building materials and phase change materials are combined to form a new type of green building material,which can give full play to the performance of energy storage and temperature control,shorten the time for heat to be absorbed into the room,reduce energy consumption in winter heating and realize building energy conservation.Capric acid-paraffin(CA-PC) binary low-eutectic composite phase change materials were prepared by melting blending method,and the optimal mass ratio of CA-PC binary composite phase change material was determined by step cooling curve method to be 0.81:0.19,and the eutectic temperature was 27.4 ℃.It was found that CA and PC were combined by physical action by Fourier infrared spectrometer(FT-IR).And 500 times of accelerated melting-freezing cycling showed that the CA-PC composite phase change material had good thermal cycle stability.In addition,the differential scanning calorimeter(DSC) analysis showed that the phase change temperature of CA-PC was 27.0 ℃ and the latent heat of phase change was 153.7 J/g,which is consistent with the eutectic temperature obtained by the step cooling curve.It is further indicated that the composite phase change material has great development potential in the field of preparation of new building energy storage materials.