喻强, 汪宏斌, 陈卓, 秦子威, 周科. 相对湿度对PEMFC膜电极影响的数值模拟[J]. 太阳能学报, 2021, 42(12): 343-348. DOI: 10.19912/j.0254-0096.tynxb.2019-1429
引用本文: 喻强, 汪宏斌, 陈卓, 秦子威, 周科. 相对湿度对PEMFC膜电极影响的数值模拟[J]. 太阳能学报, 2021, 42(12): 343-348. DOI: 10.19912/j.0254-0096.tynxb.2019-1429
Yu Qiang, Wang Hongbin, Chen Zhuo, Qin Ziwei, Zhou Ke. NUMERICAL SIMULATION OF INFLUENCE OF RELATIVE HUMIDITY ON PEMFC MEMBRANE ELECTRODE ASSEMBLY[J]. Acta Energiae Solaris Sinica, 2021, 42(12): 343-348. DOI: 10.19912/j.0254-0096.tynxb.2019-1429
Citation: Yu Qiang, Wang Hongbin, Chen Zhuo, Qin Ziwei, Zhou Ke. NUMERICAL SIMULATION OF INFLUENCE OF RELATIVE HUMIDITY ON PEMFC MEMBRANE ELECTRODE ASSEMBLY[J]. Acta Energiae Solaris Sinica, 2021, 42(12): 343-348. DOI: 10.19912/j.0254-0096.tynxb.2019-1429

相对湿度对PEMFC膜电极影响的数值模拟

NUMERICAL SIMULATION OF INFLUENCE OF RELATIVE HUMIDITY ON PEMFC MEMBRANE ELECTRODE ASSEMBLY

  • 摘要: 膜电极是质子交换膜燃料电池的核心部件,为研究相对湿度对燃料电池膜电极的影响,建立交指型燃料电池膜电极的等温稳态二维模型,分析阴阳极反应气体的相对温度分别为30%、50%、70%和90%时,燃料电池的输出性能、扩散层流场、催化层气体浓度分布、膜电极中离聚物状态和膜电极的温度分布。结果表明,随着相对湿度的增大,燃料电池的最大输出功率密度、离聚物的电导率均增加,膜电极温度升高,催化层中H2和O2摩尔体积浓度减小;当相对湿度由30%增至90%时,燃料电池最大输出功率密度提升1.7倍。通过上述方法可揭示膜电极内物理化学变化规律,同时为优化燃料电池入口气体相对湿度提供理论依据。

     

    Abstract: Membrane electrode assembly(MEA)is the core component of proton exchange membrane fuel cells(PEMFC). In order to study the influence of relative humidity on MEA,a two dimensional isothermal steady state model of the interdigitated flow field MEA is established. The PEMFC output performance,gas diffusion layer flow field,catalyst layer concentration field,ionomer properties and temperature distribution of MEA are analyzed under the same gas relative humidity of 30%,50%,70% and 90% at the inlet of anode and cathode. The results show that with the increase of relative humidity,the maximum output power density,the conductivity of ionomer and the temperature of MEA increase,but the molar concentration of hydrogen and oxygen in the catalytic layer decrease. The relative humidity increasing from 30% to 90%,the PEMFC maximum output power density increases by 1.7 times. Through numerical simulation,the physical and chemical changes in MEA can be revealed,which can provide the theoretical basis for optimizing the relative humidity of PEMFC inlet gas.

     

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