吴晓东, 邢泽炳, 谷晓霞, 张瑞卿. 炭化温度对柠条生物炭结构和性能的影响[J]. 太阳能学报, 2021, 42(12): 297-303. DOI: 10.19912/j.0254-0096.tynxb.2019-1424
引用本文: 吴晓东, 邢泽炳, 谷晓霞, 张瑞卿. 炭化温度对柠条生物炭结构和性能的影响[J]. 太阳能学报, 2021, 42(12): 297-303. DOI: 10.19912/j.0254-0096.tynxb.2019-1424
Wu Xiaodong, Xing Zebing, Gu Xiaoxia, Zhang Ruiqing. IMPACT OF CARBONIZATION TEMPERATURE ON STRUCTURE AND PROPERTIES OF Caragana korshinskii Kom BIOCHAR[J]. Acta Energiae Solaris Sinica, 2021, 42(12): 297-303. DOI: 10.19912/j.0254-0096.tynxb.2019-1424
Citation: Wu Xiaodong, Xing Zebing, Gu Xiaoxia, Zhang Ruiqing. IMPACT OF CARBONIZATION TEMPERATURE ON STRUCTURE AND PROPERTIES OF Caragana korshinskii Kom BIOCHAR[J]. Acta Energiae Solaris Sinica, 2021, 42(12): 297-303. DOI: 10.19912/j.0254-0096.tynxb.2019-1424

炭化温度对柠条生物炭结构和性能的影响

IMPACT OF CARBONIZATION TEMPERATURE ON STRUCTURE AND PROPERTIES OF Caragana korshinskii Kom BIOCHAR

  • 摘要: 为了解炭化温度对柠条生物炭性能的影响,将柠条分别在300、400、500和600℃条件下热解制备生物炭(炭化1 h),测定柠条生物炭的炭得率、工业组成、比表面积等基本特征,并通过红外光谱、元素分析等方法分析生物炭的组成,基于低温氮气吸附对柠条生物炭进行孔结构分析,并利用FHH模型进行孔隙分形维数计算。研究结果表明,随着炭化温度的升高,柠条生物炭的炭得率、挥发分、C含量均逐渐增大,极性减弱,芳香性增强,而工业组成中的固定碳、灰分则不断增大;当炭化温度从300℃升至600℃时,生物炭的比表面积和总孔容分别由1.2903 m2/g和0.0045 cm3/g逐渐增至146.5849 m2/g和0.1030 cm3/g。此外,随着炭化温度的升高,柠条生物炭的表面官能团种类逐渐减少,而且在不同炭化温度下制备的柠条生物炭的分形维数D满足2≤D≤3,可较好地表征孔隙结构的复杂性和不均匀性。

     

    Abstract: In order to understand the impact of carbonization temperature on the properties of Caragana korshinskii Kom biochars,Caragana korshinskii Kom were charred to make biochars in the temperature of 300,400,500 and 600℃(carbonization for 1 h).The basis characteristics of biochars,such as char yield of biochars,industrial components and specific surface area,were measured.The compositions of biochars were analyzed via infrared spectroscopy and elemental analysis,the pore structure analysis of biochars was performed based on cryogenic nitrogen adsorption.Moreover,the pore fractal dimension was calculated with the FHH model.The research results show that with the increase of carbonization temperature,the char yield volatile component and carbon content of biochars gradually increase gradually,the polarity weakenes,the aromaticity increases,the industrial components such as fixed carbon and ash content continuously increase.The specific surface area and total pore volume of biochars gradually increase from 1.2903 m~2/g and 0.0045 cm~3/g to 146.5849 m~2/g and 0.1030 cm~3/g,respectively,when the carbonization temperature raised from 300℃to 600℃.In addition,the surface functional groups of biochars decreased gradually with the increase of carbonization temperature.The fractal dimension D of biochars charred at different temperatures satisfies 2≤D≤3,which can well represent the complexity and inhomogeneity of its pore structure.

     

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