周忠信, 陈新亮, 张云龙, 魏长春, 赵颖, 张晓丹. RPD技术生长ICO∶H薄膜及其在晶体硅异质结太阳电池中的应用[J]. 太阳能学报, 2021, 42(1): 50-55. DOI: 10.19912/j.0254-0096.tynxb.2018-0847
引用本文: 周忠信, 陈新亮, 张云龙, 魏长春, 赵颖, 张晓丹. RPD技术生长ICO∶H薄膜及其在晶体硅异质结太阳电池中的应用[J]. 太阳能学报, 2021, 42(1): 50-55. DOI: 10.19912/j.0254-0096.tynxb.2018-0847
Zhou Zhongxin, Chen Xinliang, Zhang Yunlong, Wei Changchun, Zhao Ying, Zhang Xiaodan. RPD-GROWN ICO∶H THIN FILMS FOR CRYSTALLINE SILLICON HETEROJUNCTION SOLAR CELLS[J]. Acta Energiae Solaris Sinica, 2021, 42(1): 50-55. DOI: 10.19912/j.0254-0096.tynxb.2018-0847
Citation: Zhou Zhongxin, Chen Xinliang, Zhang Yunlong, Wei Changchun, Zhao Ying, Zhang Xiaodan. RPD-GROWN ICO∶H THIN FILMS FOR CRYSTALLINE SILLICON HETEROJUNCTION SOLAR CELLS[J]. Acta Energiae Solaris Sinica, 2021, 42(1): 50-55. DOI: 10.19912/j.0254-0096.tynxb.2018-0847

RPD技术生长ICO∶H薄膜及其在晶体硅异质结太阳电池中的应用

RPD-GROWN ICO∶H THIN FILMS FOR CRYSTALLINE SILLICON HETEROJUNCTION SOLAR CELLS

  • 摘要: 通过反应等离子体沉积(RPD)技术室温下生长掺铈的氧化铟薄膜,且沉积过程中通入氢气。高迁移率可使透明导电薄膜在较低的电阻率时保持较高的近红外透过率;透明导电薄膜中较低的载流子浓度能够减少自由载流子的吸收。迁移率的大小主要由薄膜内的散射机制决定,并且受薄膜非晶结构制约。ICO∶H薄膜表面平整,在近红外长波段透过率超过80%。在氢气流量为2 sccm时,薄膜获得1.34×10-3Ω·cm的最低电阻率和94 cm2/Vs的高迁移率。在晶体硅异质结(SHJ)太阳电池应用中,获得了较高的短路电流密度38.44 mA/cm2,相应的转换效率为16.68%。

     

    Abstract: The Cerium-doped indium oxide films are grown at room temperature by reactive plasma deposition(RPD),hydrogen is introduced during the deposition process. High mobility enables transparent conductive films to maintain higher near infrared transmittance at lower resistivity. The lower carrier concentration in transparent conductive films can reduce the absorption of free carriers. The mobility is mainly determined by the scattering mechanism in the films and is restricted by the amorphous structure of the films. The ICO∶H films have smooth surface and its transmittance is over 80% in the near-infrared long wavelength range. When hydrogen flow rate is 2 sccm,the film presents the lowest resistivity of 1.34 × 10-3Ω · cm and high mobility of 94 cm~2/Vs. In the application of crystalline silicon heterojunction(SHJ)solar cells,a higher short-circuit current of 38.44 mA/cm~2 is obtained and the corresponding conversion efficiency is 16.68%.

     

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