周仁武, 屈仲平, 孙静, 高钰婷, 刘志杰, 刘定新. 大气压低温等离子体固氮技术研究进展[J]. 高电压技术, 2023, 49(9): 3640-3653. DOI: 10.13336/j.1003-6520.hve.20230277
引用本文: 周仁武, 屈仲平, 孙静, 高钰婷, 刘志杰, 刘定新. 大气压低温等离子体固氮技术研究进展[J]. 高电压技术, 2023, 49(9): 3640-3653. DOI: 10.13336/j.1003-6520.hve.20230277
ZHOU Renwu, QU Zhongping, SUN Jing, GAO Yuting, LIU Zhijie, LIU Dingxin. Recent Progress of Atmospheric-pressure Low-temperature Plasma-enabled Nitrogen Fixation Technology[J]. High Voltage Engineering, 2023, 49(9): 3640-3653. DOI: 10.13336/j.1003-6520.hve.20230277
Citation: ZHOU Renwu, QU Zhongping, SUN Jing, GAO Yuting, LIU Zhijie, LIU Dingxin. Recent Progress of Atmospheric-pressure Low-temperature Plasma-enabled Nitrogen Fixation Technology[J]. High Voltage Engineering, 2023, 49(9): 3640-3653. DOI: 10.13336/j.1003-6520.hve.20230277

大气压低温等离子体固氮技术研究进展

Recent Progress of Atmospheric-pressure Low-temperature Plasma-enabled Nitrogen Fixation Technology

  • 摘要: 大气压低温等离子体技术因其温和、环保、经济等特点,已成为目前绿色固氮方向的研究热点。为此,主要对近几年来国内外大气压低温等离子体固氮研究进行概述,包括对等离子体活化固氮过程中的氧化和还原反应路径,不同催化剂、反应装置以及放电参数等实验条件对固氮性能的影响进行了总结与归纳。基于研究现状,进一步分析了等离子体固氮技术面临的主要问题与挑战,包括反应机理的深入探究、转化率如何进一步提高以及产业化可行性分析等问题。最后对未来大气压低温等离子体固氮技术的发展进行了展望。

     

    Abstract: Recently, atmospheric-pressure low-temperature plasma technology has attracted extensive attention in sustainable nitrogen fixation due to its mild, environmentally friendly and economic characteristics. We summarize the state-of-the-art of oxidation and reduction processes of nitrogen fixation enabled by the plasma activation, especially in terms of their different reaction pathways, and analyze and effects of different catalysts, plasma reactors and other discharge conditions on the nitrogen fixation performances. Based on the current research status, challenges of the plasma-enabled nitrogen fixation technology are outlined, including more insights into the nitrogen fixation mechanism and how to enhance the energy yields for nitrogen conversion and industrialization feasibility. Finally, future developments in atmospheric pressure low-temperature plasma nitrogen fixation technology are proposed.

     

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