Abstract:
The doping of rare earth elements can significantly improve the voltage gradient (
E1mA) of ZnO varistors, whereas it will lead to an increase in the leakage current, thereby reducing the aging stability of ZnO varistors. In order to solve the problem of increasing leakage current caused by doping rare earth elements, the influences of Y
2O
3, Ga
2O
3 and B
2O
3 co-doping on the microstructure and electrical properties of ZnO varistors were studied in this paper. The doped Y
2O
3 can significantly inhibit the growth of ZnO grains and increase the
E1mA of the sample through the pinning effect. The doping of Ga
2O
3 helps to increase the barrier height (
φb) of the grain boundary layer and restrain the increase of leakage current density (
JL).The doping of B
2O
3 is helpful to improve the liquid phase sintering of the sample and avoid the occurrence of Y spinel phase aggregation with high resistivity, and the blocking of the transmission channel is beneficial to reduce the
JL of the sample. In addition, the doping of B
2O
3 can promote the ion exchange between ZnO grains and other additives at the grain boundary, so that
φb can be effectively improved and its
JL can be further reduced. In this paper, ZnO varistors with relatively excellent comprehensive performance were obtained by co-doping Y
2O
3, Ga
2O
3 and B
2O
3, of which the voltage gradient (
E1mA) is 466 V/mm, the leakage current density (
JL) is 0.41 A/cm
2, and its nonlinear coefficient is 95. The successful development of high gradient and low leakage ZnO varistors is of great significance for solving the problem of uneven distribution of the overall potential of metal oxide arrester.