周远翔, 杨达, 姜贵敏, 滕陈源, 张云霄, 姚彤. Y2O3掺杂对钛酸锶钡陶瓷材料介电–温度及电阻率–温度特性的影响[J]. 高电压技术, 2023, 49(11): 4686-4694. DOI: 10.13336/j.1003-6520.hve.20222017
引用本文: 周远翔, 杨达, 姜贵敏, 滕陈源, 张云霄, 姚彤. Y2O3掺杂对钛酸锶钡陶瓷材料介电–温度及电阻率–温度特性的影响[J]. 高电压技术, 2023, 49(11): 4686-4694. DOI: 10.13336/j.1003-6520.hve.20222017
ZHOU Yuanxiang, YANG Da, JIANG Guimin, TENG Chenyuan, ZHANG Yunxiao, YAO Tong. Effect of Y2O3 Doping on Dielectric-temperature and Resistivity-temperature Characteristics of Barium Strontium Titanate Ceramics[J]. High Voltage Engineering, 2023, 49(11): 4686-4694. DOI: 10.13336/j.1003-6520.hve.20222017
Citation: ZHOU Yuanxiang, YANG Da, JIANG Guimin, TENG Chenyuan, ZHANG Yunxiao, YAO Tong. Effect of Y2O3 Doping on Dielectric-temperature and Resistivity-temperature Characteristics of Barium Strontium Titanate Ceramics[J]. High Voltage Engineering, 2023, 49(11): 4686-4694. DOI: 10.13336/j.1003-6520.hve.20222017

Y2O3掺杂对钛酸锶钡陶瓷材料介电–温度及电阻率–温度特性的影响

Effect of Y2O3 Doping on Dielectric-temperature and Resistivity-temperature Characteristics of Barium Strontium Titanate Ceramics

  • 摘要: 钛酸钡基电介质陶瓷因具有良好的介电和正温度系数特性已被广泛应用于科技、工业以及日常生活中,在新兴领域的需求下,开发具有低居里温度和高常温电阻率特性的电介质陶瓷材料具有重要意义。因此,采用固相法制备了不同掺杂浓度氧化钇(Y2O3)的钛酸锶钡(Ba0.7Sr0.3TiO3,BST),正温度系数(positive temperature coefficient,PTC)陶瓷材料,通过X射线衍射和扫描电镜测试了试样的理化特性,利用宽频介电谱仪和电阻率–温度测量系统分别获得了试样的介电–温度特性和电阻率–温度特性,并构建了四象限模型分析钇(Y)对材料介电–温度特性和电阻率–温度特性的影响机理。研究表明:随Y2O3含量的增大,介电常数和居里温度均呈先增大后减小的趋势,而常温电阻率呈现相反的变化趋势。0.0008 mol的Y2O3掺杂可大幅提高BST材料相对介电常数(> 105)且具有较低的居里温度(34.1 ℃)和较大的常温电阻率(5.6×106 Ω·cm)。实现了低居里温度和高电阻率特性的协同调控,拓宽了PTC材料的应用范围。

     

    Abstract: Barium titanate based dielectric ceramics have been widely used in science and technology, industry and daily life because of their good dielectric and positive temperature coefficient characteristics. Under the demands of emerging fields, it is of great significance to develop dielectric ceramic materials with low Curie temperature and high room temperature resistivity characteristics. Therefore, a ceramic material doped with different concentrations of yttrium oxide (Y2O3) with positive temperature coefficient (PTC), barium strontium titanate (Ba0.7Sr0.3TiO3, BST), was prepared by the conventional solid-state reaction. The physical and chemical properties of the samples are observed by X-ray diffraction and scanning electron microscope. The broadband dielectric spectrometer and resistivity-temperature measurement system are used to obtain the dielectric-temperature properties and resistivity-temperature characteristics of the samples, and a four-quadrant model is constructed to analyze the influence mechanism of yttrium (Y) on the dielectric-temperature properties and resistivity-temperature characteristics of the material. The results show that the relative permittivity and Curie temperature increase first and then decrease with the increase of Y2O3 content, while the resistivity at room temperature shows an opposite trend. The relative permittivity (> 105) can be significantly increased by doping 0.0008 mol Y2O3, and has a lower Curie temperature (34.1 ℃) and a higher resistivity at room temperature (5.6×106 Ω·cm). The synergistic regulation of low Curie temperature and high resistivity characteristics is realized, which broadens the application range of PTC materials.

     

/

返回文章
返回