朱中旭, 陈思雨, 金余其. 模拟村镇垃圾热解气及焦油特性研究[J]. 发电设备, 2024, 38(6): 356-363. DOI: 10.19806/j.cnki.fdsb.2024.06.004
引用本文: 朱中旭, 陈思雨, 金余其. 模拟村镇垃圾热解气及焦油特性研究[J]. 发电设备, 2024, 38(6): 356-363. DOI: 10.19806/j.cnki.fdsb.2024.06.004
Zhu Zhongxu, Chen Siyu, Jin Yuqi. Study on Characteristics of Pyrolysis Gas and Tar from Simulated Rural Solid Waste[J]. POWER eQUIPMENT, 2024, 38(6): 356-363. DOI: 10.19806/j.cnki.fdsb.2024.06.004
Citation: Zhu Zhongxu, Chen Siyu, Jin Yuqi. Study on Characteristics of Pyrolysis Gas and Tar from Simulated Rural Solid Waste[J]. POWER eQUIPMENT, 2024, 38(6): 356-363. DOI: 10.19806/j.cnki.fdsb.2024.06.004

模拟村镇垃圾热解气及焦油特性研究

Study on Characteristics of Pyrolysis Gas and Tar from Simulated Rural Solid Waste

  • 摘要: 在连续给料式固定床装置上研究了模拟村镇垃圾在不同组分配比下对热解气及焦油产生特性的影响。试验结果表明:在800 ℃垃圾混合热解比单独热解更能促进物料充分裂解,减少焦油产生并提高热解气冷煤气效率(CGE)。混合热解能降低焦油中O元素的含量,降低焦油的腐蚀性;含氯物质(本文中为聚氯乙烯)的存在能有效促进热解焦油中含N、S官能团的分解,保证焦油具有更高的热值和更好的稳定性。混合热解能有效减少焦油中的杂环及脂环化合物,但开链化合物及芳香化合物占比变化情况则与物料中的组分配比有关。

     

    Abstract: In a continuous feeding fixed bed furnace, researches were conducted on the influence of simulated rural solids with different component proportions on the producing characteristics of pyrolysis gas and tar. Experimental results show that, compared with single component, the pyrolysis of rural solid waste with mixed components is more conducive to promoting the sufficient cracking of materials, reducing the tar production, and improving the cold gas efficiency (CGE) when the pyrolysis temperature is 800 ℃. The pyrolysis with mixed components can reduce the content of O element and corrosivity of tar, while the presence of chlorine-containing substance (polyvinyl chloride in this paper) could effectively promote the decomposition of functional groups containing N or S element in pyrolysis tar, which ensures that tar has a higher heat value and a better stability. The pyrolysis with mixed components is effective in reducing heterocyclic and alicyclic compounds in tar, but the proportion change of chain compounds and aromatic compounds is related to the component proportions of simulated rural solid waste.

     

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