热解型Fe-N-C催化剂在燃料电池阴极氧还原反应中的应用研究进展

孙寒雪; 李孟雪; 焦芮; 李吉焱; 朱照琪; 李安

doi:doi:10.19912/j.0254-0096.tynxb.2024-1459

English Version Reader LoginJournal Login

您当前的位置：

首页 >

文章列表页 >

热解型Fe-N-C催化剂在燃料电池阴极氧还原反应中的应用研究进展

更新时间：2026-01-08

- 热解型Fe-N-C催化剂在燃料电池阴极氧还原反应中的应用研究进展
- Vol. 46, Issue 12, Pages: 29-40(2025)
- 作者机构：
- 作者简介：
- 基金信息：
- DOI：doi:10.19912/j.0254-0096.tynxb.2024-1459
  CLC： TQ150
- Published Online：07 January 2026，
  
  Published：2025
- 稿件说明：
移动端阅览
孙寒雪, 李孟雪, 焦芮, et al. 热解型Fe-N-C催化剂在燃料电池阴极氧还原反应中的应用研究进展[J]. 2025, 46(12): 29-40.
DOI：

孙寒雪, 李孟雪, 焦芮, et al. 热解型Fe-N-C催化剂在燃料电池阴极氧还原反应中的应用研究进展[J]. 2025, 46(12): 29-40. DOI： doi:10.19912/j.0254-0096.tynxb.2024-1459.

摘要

该文总结了近年来铁氮共掺杂碳基催化剂（Fe‑N‑C）的制备策略和合成方法（模板法、浸渍法、原位捕获法等）

重点梳理了以金属有机框架、有机多孔聚合物和生物质为前驱体制备热解型Fe-N-C催化剂的研究现状

讨论了Fe-N-C催化剂中活性位点的结构和反应机制

同时对该材料领域当前存在的挑战和未来重点发展方向进行了总结和展望。

Abstract

In this review

the preparation strategy and synthetic methods of Fe-N-C catalysts in recent years including template method

impregnation method and in situ capture method etc are systematicauy summarized. The current developments of pyrolytic Fe-N-C catalysts derived from metal-organic frameworks

organic porous polymers and biomass are emphatically outlined. The structure of active sites and reaction mechanism in Fe-N-C catalysts are also discussed. Then

the challenges and future development directions of Fe-N-C catalysts for ORR are discussed and summarized.

关键词

Keywords

references

PAN X Z, SHAO T M, ZHENG X Z, et al.Energy and sustainable development nexus: a review[J]. Energy strategy reviews, 2023, 47: 101078.

KANNAIYAN K, LEKSHMI G S, RAMAKRISHNA S, et al.Perspectives for the green hydrogen energy-based economy[J]. Energy, 2023, 284: 129358.

YANG L J, SHUI J L, DU L, et al.Carbon-based metal-free ORR electrocatalysts for fuel cells: past, present, and future[J]. Advanced materials, 2019, 31(13): 1804799.

NANADEGANI F S, SUNDEN B.Review of exergy and energy analysis of fuel cells[J]. International journal of hydrogen energy, 2023, 48(84): 32875-32942.

LIU M Y, XIAO X D, LI Q, et al.Recent progress of electrocatalysts for oxygen reduction in fuel cells[J]. Journal of colloid and interface science, 2022, 607: 791-815.

ZHAN F, HU K S, MAI J H, et al.Recent progress of Pt-based oxygen reduction reaction catalysts for proton exchange membrane fuel cells[J]. Rare metals, 2024, 43(6): 2444-2468.

程庆庆, 陈驰, 邹亮亮, 等. 当前实用和未来发展Pt-非Pt氧还原电催化剂研究进展[J]. 太阳能学报, 2022, 43(6): 335-344.

XU H M, ZHU H R, HUANG C J, et al.Recent advances in Fe-N-C- and Co-N-C-based materials as bifunctional electrocatalysts for oxygen reduction and oxygen evolution[J]. Science China chemistry, 2024, 67(4): 1137-1160.

XIA P, WANG C H, HE Q, et al.MOF-derived single-atom catalysts: the next frontier in advanced oxidation for water treatment[J]. Chemical engineering journal, 2023, 452: 139446.

LI H Y, PAN F P, QIN C, et al.Porous organic polymers-based single-atom catalysts for sustainable energy-related electrocatalysis[J]. Advanced energy materials, 2023, 13(28): 2301378.

REN G H, SUN W, CHEN Y T, et al.Synthesis of biomass nitrogen-doped catalysts and their electrocatalytic performance in fuel cells[J]. Journal of physics: conference series, 2024, 2757(1): 012009.

YANG Z L, CHEN Y Z, ZHANG S M, et al.Identification and understanding of active sites of non-noble iron-nitrogen-carbon catalysts for oxygen reduction electrocatalysis[J]. Advanced functional materials, 2023, 33(26): 2215185.

BAE G, KIM M M, HAN M H, et al.Unravelling the complex causality behind Fe-N-C degradation in fuel cells[J]. Nature catalysis, 2023, 6(12): 1140-1150.

ZENG Y C, LI C Z, LI B Y, et al.Tuning the thermal activation atmosphere breaks the activity-stability trade-off of Fe-N-C oxygen reduction fuel cell catalysts[J]. Nature catalysis, 2023, 6: 1215-1227.

LEFEVRE M, PROIETTI E, JAOUEN F, et al. Iron-based catalysts with improved oxygen reduction activity in polymer electrolyte fuel cells[J]. Science, 2009, 324(5923): 71-74.

HE Y H, YANG S W, PRIEST C, et al.Atomically dispersed metal-nitrogen-carbon catalysts for fuel cells: advances in catalyst design, electrode performance, and durability improvement[J]. Chemical society reviews, 2020, 49: 3484-3524.

WANG Y, LIU W X, WANG R Z, et al.Preparation of high-efficiency Fe/N-doped carbon catalysts derived from graphite phase carbon nitride for reduction of oxygen[J]. Catalysts, 2024, 14(4): 279.

JUNAIDI N H A, WONG W Y, LOH K S, et al. Enhanced oxygen reduction reaction catalyst stability and durability of MXene-supported Fe-N-C catalyst for proton exchange membrane fuel cell application[J]. Journal of alloys and compounds, 2023, 968: 171898.

STODOLKA M, CHOI J Y, FLOOD J, et al.Iron-based 2D conductive metal-organic framework nanostructure with enhanced pseudocapacitance[J]. ACS applied nano materials, 2022, 5(2): 2156-2162.

MARTINAIOU I, MONTEVERDE VIDELA A H A, WEIDLER N, et al. Activity and degradation study of an Fe-N-C catalyst for ORR in direct methanol fuel cell (DMFC)[J]. Applied catalysis B: environmental, 2020, 262: 118217.

WANG Q, LU R H, YANG Y Q, et al.Tailoring the microenvironment in Fe-N-C electrocatalysts for optimal oxygen reduction reaction performance[J]. Science bulletin, 2022, 67(12): 1264-1273.

LI R X, HAO Y, LIU Y H, et al.Short nanotubular Fe-N-C catalysts with curved catalytic sites and contributing regions for oxygen reduction reaction[J]. Journal of alloys and compounds, 2024, 984: 174002.

FENG Y Y, HU H S, LIU R J, et al.FeNC catalysts with high catalytic activity and stability for oxygen reduction reaction[J]. Chinese journal of structural chemistry, 2022, 41(9): 2209080-2209086.

LI Q L, LIU H, ZHANG L C, et al.Highly efficient Fe-N-C oxygen reduction electrocatalyst engineered by sintering atmosphere[J]. Journal of power sources, 2020, 449: 227497.

YU F, BAI X T, LIANG M X, et al.Recent progress on metal-organic framework-derived porous carbon and its composite for pollutant adsorption from liquid phase[J]. Chemical engineering journal, 2021, 405: 126960.

DU M X, LI D, LIU S Z, et al.Practical classification of catalysts for oxygen reduction reactions: optimization strategies and mechanistic analysis[J]. Advanced functional materials, 2023, 33(29): 2301527.

ZHANG L H, SHI Y M, WANG Y, et al.Nanocarbon catalysts: recent understanding regarding the active sites[J]. Advanced science, 2020, 7(5): 1902126.

QUÍLEZ-BERMEJO J, MORALLÓN E, CAZORLA-AMORÓS D. Metal-free heteroatom-doped carbon-based catalysts for ORR: a critical assessment about the role of heteroatoms[J]. Carbon, 2020, 165: 434-454.

WANG Y, KONG A G, CHEN X T, et al.Efficient oxygen electroreduction: hierarchical porous Fe-N-doped hollow carbon nanoshells[J]. ACS catalysis, 2015, 5(6): 3887-3893.

SHAO C F, ZHUANG S G, ZHANG H C, et al.Enhancement of mass transport for oxygen reduction reaction using petal-like porous Fe-NC nanosheet[J]. Small, 2021, 17(6): 2006178.

TAN H B, LI Y Q, KIM J, et al.Sub-50 nm iron-nitrogen-doped hollow carbon sphere-encapsulated iron carbide nanoparticles as efficient oxygen reduction catalysts[J]. Advanced science, 2018, 5(7): 1800120.

DA SILVA FREITAS W, MACHADO PICO P P, D’EPIFANIO A, et al. Nanostructured Fe-N-C as bifunctional catalysts for oxygen reduction and hydrogen evolution[J]. Catalysts, 2021, 11(12): 1525.

XU J C, LIANG G F, CHEN D, et al.Iron and nitrogen doped carbon derived from ferrocene and ZIF-8 as proton exchange membrane fuel cell cathode catalyst[J]. Applied surface science, 2022, 573: 151607.

TADAVANI K F, ZHIANI M, GHARIBI H, et al.Preparation of a high-performance Fe-N-C electrocatalyst from an MOF precursor for ORR toward zinc-air batteries[J]. Energy & fuels, 2023, 37(23): 19092-19102.

MA S Q, GOENAGA G A, CALL A V, et al.Cobalt imidazolate framework as precursor for oxygen reduction reaction electrocatalysts[J]. Chemistry-A European journal, 2011, 17(7): 2063-2067.

PROIETTI E, JAOUEN F, LEFÈVRE M, et al. Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells[J]. Nature communications, 2011, 2: 416.

JIAO L, WAN G, ZHANG R, et al.From metal-organic frameworks to single-atom Fe implanted N-doped porous carbons: efficient oxygen reduction in both alkaline and acidic media[J]. Angewandte chemie international edition, 2018, 57(28): 8525-8529.

LIN C Y, ZHANG D T, ZHAO Z H, et al.Covalent organic framework electrocatalysts for clean energy conversion[J]. Advanced materials, 2018, 30(5): 1703646.

DENG Y, WANG Y, XIAO X, et al.Progress in hybridization of covalent organic frameworks and metal-organic frameworks[J]. Small, 2022, 18(38): 2202928.

CÔTÉ A P, BENIN A I, OCKWIG N W, et al. Porous, crystalline, covalent organic frameworks[J]. Science, 2005, 310(5751): 1166-1170.

ZHANG W D, ZHOU L, SHI Y X, et al.Dual-atom catalysts derived from a preorganized covalent organic framework for enhanced electrochemical oxygen reduction[J]. Angewandte chemie international edition, 2023, 62(27): e202304412.

LEE J M, COOPER A I.Advances in conjugated microporous polymers[J]. Chemical reviews, 2020, 120(4): 2171-2214.

BRÜLLER S, LIANG H W, KRAMM U I, et al. Bimetallic porous porphyrin polymer-derived non-precious metal electrocatalysts for oxygen reduction reactions[J]. Journal of materials chemistry A, 2015, 3(47): 23799-23808.

SUN H X, WANG J J, LI M X, et al.Rational design of Fe, N Co-doped porous carbon derived from conjugated microporous polymer as an electrocatalytic platform for oxygen reduction reaction[J]. Journal of colloid and interface science, 2024, 673: 354-364.

SUN H X, ZHOU P L, TIAN Z Y, et al.Non-precious metal-doped carbon materials derived from porphyrin-based porous organic polymers for oxygen reduction electrocatalysis[J]. ChemPlusChem, 2022, 87(7): e202200168.

PELES-STRAHL L, HONIG H C, PERSKY Y, et al.Modular iron-bipyridine-based conjugated aerogels as catalysts for oxygen reduction reaction[J]. ACS catalysis, 2023, 13(21): 14377-14384.

WANG M Y, CAO Z L, LI L Y, et al.Porous Fe, N Co-doped carbon with high electrocatalytic oxygen reduction reaction performance in Zn-air battery[J]. Carbon, 2022, 200: 337-346.

孙寒雪, 王娟娟, 朱照琪, 等. 燃料电池氧还原反应中的多孔有机聚合物衍生碳基电催化剂[J]. 化学进展, 2023, 35(11): 1638-1654.

ZHU Z Q, CUI J, CAO X Y, et al.Synthesis and electrocatalytic properties of M (Fe, Co), N Co-doped porous carbon frameworks for efficient oxygen reduction reaction[J]. International journal of hydrogen energy, 2022, 47(16): 9504-9516.

HE H Z, ZHANG R Q, ZHANG P C, et al.Functional carbon from nature: biomass-derived carbon materials and the recent progress of their applications[J]. Advanced science, 2023, 10(16): 2205557.

YU L Q, WANG H, CHEN S L, et al.Biomass derived Fe-N/C catalyst for efficiently catalyzing oxygen reduction reaction in both alkaline and neutral pH conditions[J]. Chinese chemical letters, 2023, 34(1): 107236.

LUO X L, LIU Z, MA Y P, et al.Biomass derived Fe, N-doped carbon material as bifunctional electrocatalysts for rechargeable Zn-air batteries[J]. Journal of alloys and compounds, 2021, 888: 161464.

SHI M H, MA J H, YAO Z Z, et al.Iron and nitrogen Co-doped porous carbon derived from soybean dregs with enhanced catalytic performance for oxygen reduction[J]. Journal of electroanalytical chemistry, 2019, 839: 141-148.

JIA X Y, ZHANG C X, ZHANG Y C, et al.Air cathode performance of Fe/N/Cs synthesized from legume biomasses in microbial fuel cells[J]. Industrial crops and products, 2024, 212: 118394.

CAO Y, SUN Y G, WANG H W, et al.Fundamental understanding of nitrogen in biomass electrocatalysts for oxygen reduction and zinc-air batteries[J]. iScience, 2024, 27(2): 108913.

张鹏, 李佳烨, 潘原. 单原子催化剂在氢燃料电池阴极氧还原反应中的研究进展[J].太阳能学报, 2022, 43(6): 306-320.

PAYATTIKUL L, CHEN C Y, CHEN Y S, et al.Recent advances and synergistic effects of non-precious carbon-based nanomaterials as ORR electrocatalysts: a review[J]. Molecules, 2023, 28(23): 7751.

张明焱, 刘燕, 张雪婷, 等. 非贵金属双功能催化剂在锌空气电池研究进展[J]. 化工进展, 2023, 42(S1): 276-286.

MA S Y, HAN W G, HAN W L, et al.Recent advances and future perspectives in MOF-derived single-atom catalysts and their application: a review[J]. Journal of materials chemistry A, 2023, 11(7): 3315-3363.

HE T X, ZHANG X Y, LI D, et al.Hierarchical-pore-stabilization strategy for fabricating 18.3 wt% high-loading single-atom catalyst for oxygen reduction reaction[J]. Small, 2024, 20(17): 2308530.

AO X, DING Y, NAM G, et al.A single-atom Fe-N-C catalyst with ultrahigh utilization of active sites for efficient oxygen reduction[J]. Small, 2022, 18(30): 2203326.

ZHANG P, CHEN H C, ZHU H Y, et al.Inter-site structural heterogeneity induction of single atom Fe catalysts for robust oxygen reduction[J]. Nature communications, 2024, 15: 2062.

LIAN Y B, XU J N, ZHOU W K, et al.Research progress on atomically dispersed Fe-N-C catalysts for the oxygen reduction reaction[J]. Molecules, 2024, 29(4): 771.

SHEN H J, THOMAS T, RASAKI S A, et al.Oxygen reduction reactions of Fe-N-C catalysts: current status and the way forward[J]. Electrochemical energy reviews, 2019, 2(2): 252-276.

MA Q L, JIN H H, ZHU J W, et al.Stabilizing Fe-N-C catalysts as model for oxygen reduction reaction[J]. Advanced science, 2021, 8(23): 2102209.

WEI J, XIA D S, WEI Y P, et al.Probing the oxygen reduction reaction intermediates and dynamic active site structures of molecular and pyrolyzed Fe-N-C electrocatalysts by in situ Raman spectroscopy[J]. ACS catalysis, 2022, 12(13): 7811-7820.

WANG X P, FERRANDON M, PARK J H, et al.Iron redox behavior and oxygen reduction activity of Fe-N-C electrocatalysts in different electrolytes[J]. Electrochimica acta, 2023, 443: 141934.

WAN X, LIU X F, LI Y C, et al.Fe-N-C electrocatalyst with dense active sites and efficient mass transport for high-performance proton exchange membrane fuel cells[J]. Nature catalysis, 2019, 2(3): 259-268.

WANG Y, WANG M H, CHEN T, et al.Pyrazine-linked iron-coordinated tetrapyrrole conjugated organic polymer catalyst with spatially proximate donor-acceptor pairs for oxygen reduction in fuel cells[J]. Angewandte Chemie international edition, 2023, 62(47): e202308070.

ZHAO K M, LIU S Q, LI Y Y, et al.Insight into the mechanism of axial ligands regulating the catalytic activity of Fe-N4 sites for oxygen reduction reaction[J]. Advanced energy materials, 2022, 12(11): 2103588.

JIA Y, XIONG X Y, WANG D N, et al.Atomically dispersed Fe-N4 modified with precisely located S for highly efficient oxygen reduction[J]. Nano-micro letters, 2020, 12(1): 116.

FU X G, ZAMANI P, CHOI J Y, et al.In situ polymer graphenization ingrained with nanoporosity in a nitrogenous electrocatalyst boosting the performance of polymer-electrolyte-membrane fuel cells[J]. Advanced materials, 2017, 29(7): 1604456.

LEFÈVRE M, DODELET J P, BERTRAND P. Molecular oxygen reduction in PEM fuel cells: evidence for the simultaneous presence of two active sites in Fe-based catalysts[J]. The journal of physical chemistry B, 2002, 106(34): 8705-8713.

SONG P, WANG Y, PAN J, et al.Structure-activity relationship in high-performance iron-based electrocatalysts for oxygen reduction reaction[J]. Journal of power sources, 2015, 300: 279-284.

FERRANDON M, KROPF A J, MYERS D J, et al.Multitechnique characterization of a polyaniline-iron-carbon oxygen reduction catalyst[J]. The journal of physical chemistry C, 2012, 116(30): 16001-16013.

ZHU Y S, ZHANG B S, LIU X, et al.Unravelling the structure of electrocatalytically active Fe-N complexes in carbon for the oxygen reduction reaction[J]. Angewandte Chemie international edition, 2014, 53(40): 10673-10677.

Views

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

ADVANCES IN CURRENT PRACTICAL AND FUTURE DEVELOPMENT OF Pt-NON-Pt OXYGEN REDUCTION REACTION ELECTROCATALYST

考虑电氢转化动态效率特性的工业园区氢储能容量优化配置

SOLAR-HYDROGEN ENERGY SYSTEM AND ITS PROSPECTS

THE STUDY ON THE TECHNOLOGY OF THE HYDROGEN ENERGY GENERATE ELECTRICITY（Ⅰ）——THE EFFECT OF COMPOUND ELECTRODE MATERIAL OF PLATINUM-CARBON ON THE DISC HARGE PROPERTY OF ION EXCHANGE MEMBRANE FUEL CELLS

THE STUDY ON THE TECHNOLOGY OF THE HYDROGEN ENERGY GENERATE ELECTRICITY（Ⅱ）——THE EFFECT OF THE ELECTRODE ADDITIVES ON THE DISCHARGE PROPERTY OF THE ION EXCHANGE MEMBRANE FUEL CELLS

Related Author

Cheng Qingqing

Chen Chi

Zou Liangliang

Zou Zhiqing

Yang Hui

陈云帆

艾欣

王哲

Related Institution

Shanghai Advanced Research Institute, Chinese Academy of Sciences

General Research Institute of Non-ferrous Metals

Department of Chemical Engineer,University of Petroleum

石油大学化工学院北京102200

Department of Chemical Engineering,University of Petroleum

AI问答

⁰