a professional crystal growth simulation software developed and designed by STR
combining crystal dynamics and thermodynamics
selecting N-type monocrystalline silicon commonly used dopant phosphorus is selected
according to the polycrystalline silicon mass of 10 times to add phosphorus monomers as dopant
meanwhile selecting eight different crucible rotate speeds of 7-14 r/min and six different crystal rotate speeds of 6-11 r/min are selected
and orthogonal simulation experiments with a higher crystal pulling rate of 1.8 mm/min were conducted to obtain the change of electrical resistivity. By analyzing the parameters of inner crucible melt temperature field and flow field
outer crucible melt temperature field and flow field
solid-liquid interface
defects in the crystal
appropriate crucible rotational speed and crystal rotational speed were obtained. By comparing with the radial resistivity change obtained by converting the phosphorus concentration to the resistivity at the solid-liquid interface
the influencing mechanism of the radial resistivity of the continuous direct-drawing monocrystalline silicon was researched.
GIANNATTASIO A.A simplified model to predict resistivity profiles in continuous-feeding Cz-silicon crystals[J]. Journal of crystal growth, 2020, 542: 125686.
WANG J H.Resistivity distribution in bulk growth of silicon single crystals[J]. Journal of crystal growth, 2005, 275(1/2): e73-e78.
ZU Y B, LI S Y, LV G Q, et al.Study on the influence of the pulling rate on the axial and radial uniformity of gallium in czochralski monocrystalline silicon crystal[J]. Silicon, 2023, 15(14): 6073-6084.
XU H.Characterization of n-type mono-crystalline silicon ingots produced by continuous Czochralski (Cz) technology[J]. Energy procedia, 2015, 77: 658-664.
ANSELMO A, PRASAD V, KOZIOL J, et al.Numerical and experimental study of a solid pellet feed continuous Czochralski growth process for silicon single crystals[J]. Journal of crystal growth, 1993, 131(1/2): 247-264.
GIANNATTASIO A, GIAQUINTA A, PORRINI M.The accuracy of the standard resistivity-concentration conversion practice estimated by measuring the segregation coefficient of boron and phosphorous in Cz-Si[J]. physica status solidi (a), 2011, 208(3): 564-567.
GB/T 13389—2014, 掺硼掺磷掺砷硅单晶电阻率与掺杂剂浓度换算规程[S].
GB/T 25076—2018, 太阳能电池用硅单晶[S].
GB/T 11073—2007, 硅片径向电阻率变化的测量方法[S].
PORRINI M, SCALA R, VORONKOV V V.Behavior of volatile dopants (P, Sb) in Czochralski silicon growth[J]. Journal of crystal growth, 2017, 460: 13-15.
SCHLESINGER M E.The thermodynamic properties of phosphorus and solid binary phosphides[J]. Chemical reviews, 2002, 102(11): 4267-4301.