Online First:23 March 2016,
Published:2016
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袁娟, 郭清泉, 徐勇. 二氢杨梅素-铜配合物抗氧化活性的研究[J]. 广东工业大学学报, 2016, 33(2): 81-84.
Yuan Juan, Guo Qing-quan, Xu Yong. Study on Antioxidant Activities of the Complex of DMY-Cu(Ⅱ)[J]. 2016, 33(2): 81-84.
袁娟, 郭清泉, 徐勇. 二氢杨梅素-铜配合物抗氧化活性的研究[J]. 广东工业大学学报, 2016, 33(2): 81-84. DOI: 10.3969/j.issn.1007-7162.2016.02.016.
Yuan Juan, Guo Qing-quan, Xu Yong. Study on Antioxidant Activities of the Complex of DMY-Cu(Ⅱ)[J]. 2016, 33(2): 81-84. DOI: 10.3969/j.issn.1007-7162.2016.02.016.
首先合成氢杨梅素-铜(DMY-Cu(Ⅱ))配合物,通过紫外光谱、红外光谱、热重-热差分析(TG-DTA) 及元素分析对DMY-Cu(Ⅱ)金属配合物的结构进行表征.结果表明,DMY易与Cu
2+
形成配合物,其组成为[C
15
H
10
O
8
Cu
]
·H
2
O.进一步地研究了DMY-Cu(Ⅱ)金属配合物对超氧阴离子自由基(O
-
·)、羟基自由基(OH·)及DPPH 自由基(DPPH·)的清除作用,结果发现DMY-Cu(Ⅱ)配合物对OH·、O
· 和DPPH·具有显著的清除效果,且清除效果比单独配体DMY更强.
This paper characterizes the structure of metal complex DMY-Cu(Ⅱ)after its preparation through UV spectroscopy
IR spectroscopy
elemental analysis and thermogravimetry-differential thermal analysis (TG-DTA). The results indicate that DMY and Cu
ion are easy to form complexes whose composition is [C
O. It further studies the scavenging capacity of DMY-Cu(Ⅱ)on superoxide anion radical (O
·),hydroxyl radical (OH·)and DPPH radical(DPPH·). The finding of the investigation is that the complex DMY-Cu(Ⅱ) has a great cleaning effect on OH·
· and DPPH·
which outweighs the DMY ligand.
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