Preparation and Properties of Biodegradable Polymer Detergent Builder

Fu Shu-qin; Guo Jian-wei; Ma Qian; Chen Shao-hua; Yang Ping; Cui Yi-hua

doi:10.3969/j.issn.1007-7162.2013.04.006

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Preparation and Properties of Biodegradable Polymer Detergent Builder

更新时间：2026-05-27

- Preparation and Properties of Biodegradable Polymer Detergent Builder
- Vol. 30, Issue 4, Pages: 39-42(2013)
- 作者机构：
- 作者简介：
- 基金信息：
- DOI：10.3969/j.issn.1007-7162.2013.04.006
  CLC：
- Online First：30 December 2013，
  
  Published：2013
- 稿件说明：
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傅淑琴, 郭建维, 马倩, 陈少华, 杨平, 崔亦华. 可生物降解高分子助洗剂P(AA-co-MDO)的制备与性能[J]. 广东工业大学学报, 2013, 30(4): 39-42.

Fu Shu-qin, Guo Jian-wei, Ma Qian, et al. Preparation and Properties of Biodegradable Polymer Detergent Builder[J]. 2013, 30(4): 39-42.
傅淑琴, 郭建维, 马倩, 陈少华, 杨平, 崔亦华. 可生物降解高分子助洗剂P(AA-co-MDO)的制备与性能[J]. 广东工业大学学报, 2013, 30(4): 39-42. DOI： 10.3969/j.issn.1007-7162.2013.04.006.

Fu Shu-qin, Guo Jian-wei, Ma Qian, et al. Preparation and Properties of Biodegradable Polymer Detergent Builder[J]. 2013, 30(4): 39-42. DOI： 10.3969/j.issn.1007-7162.2013.04.006.

摘要

以丙烯酸(AA)、2-亚甲基-1

3-二氧环庚烷(MDO)为共聚反应单体，采用水溶液聚合法合成了一种绿色环保型高分子助洗剂.考察了反应时间、MDO含量、引发剂含量、聚合反应温度等对共聚产物性能的影响.结果表明：合成的P(AA-co-MDO)共聚物具有优良、可控的助洗性能和生物降解性能，钙螯合力可达到531.32 mg(CaCO

)·g

-1

，碳酸钙分散力133.03 mg(CaCO

)·g

-1

，28 d的生物降解率为62.1%.

Abstract

A novel green polymer detergent builder was prepared by solution polymerization with 2-methylene-1

3-dioxepane(MDO) and acrylic acid (AA) as monomers. The effects of reaction time

MDO content

initiator content

and polymerization temperature on the properties of copolymer were investigated. The results show that synthetic copolymer P(AA-co-MDO) has excellent but controllable washing assisting properties and biodegradability. The chelating capacity

dispersing of P(AA-co-MDO) copolymer are 531.32 mg(CaCO

)·g

-1

133.03 mg(CaCO

)·g

-1

respectively. The biodegradation rate is as high as 62.1% within 28 days.

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