Online First:30 March 2013,
Published:2013
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曾丽珍, 李伟善. 碳化钼作为微生物燃料电池阴极催化剂的研究[J]. 广东工业大学学报, 2013, 30(1): 110-114.
Zeng Li-zhen, Li Wei-shan. Mo2C as Cathodic Catalysts in Microbial Fuel Cells[J]. 2013, 30(1): 110-114. DOI: 10.3969/j.issn.1007-7162.2013.01.021.
曾丽珍, 李伟善. 碳化钼作为微生物燃料电池阴极催化剂的研究[J]. 广东工业大学学报, 2013, 30(1): 110-114. DOI: 10.3969/j.issn.1007-7162.2013.01.021.
Zeng Li-zhen, Li Wei-shan. Mo2C as Cathodic Catalysts in Microbial Fuel Cells[J]. 2013, 30(1): 110-114. DOI: 10.3969/j.issn.1007-7162.2013.01.021. DOI:
以循环伏安法(CV)和线性扫描伏安法(LSV)考察Mo2C对氧还原反应(ORR)的催化行为,并采用Mo
2
C作为阴阳极催化剂构建MFC.结果表明,Mo
C对氧还原反应有显著的催化作用,而且其催化效果随负载量增加而增强;当以肺炎克雷伯氏菌 (L17)为产电微生物、质量浓度为2 g/L的葡萄糖为燃料,阴阳极催化剂Mo
C的载量均为6.0 mg/cm
时,该MFC的最大输出功率可达1.95 W/m
3
,为之前报道所对应的Pt阴极材料的Mo
C 基MFC最大输出功率的81.5%,Pt为阴阳极催化剂的MFC的56.3%.
The electrochemical behavior of the Mo
C catalyzing ORR was studied via cyclic voltammetry and linear scanning voltammetry. Experimental results show that Mo
C has significant catalysis on ORR and the catalytic effect is enhanced with the increase of the load. When 2 g/L glucose solution was as anodic fuel
the MFC with 6 mg/cm
Mo
C delivering power density of 1.95 W/m
produced 81.5% as much power density as the MFC using Pt-catalyst cathode
and 56.3% as much power density as the MFC using Pt-catalyst cathode and anode under the same conditions.
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