Performance Study of an Integrated Ammonia Recovery and CarbonCapture Device Based on a Superamphiphobic Membrane

WANG Yubao; WANG Jing; JIANG Wei; CHEN Tao; HANS-JVRGEN Butt; QIN Hanshi; HOU Youmin

doi:10.19805/j.cnki.jcspe.2026.240735

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Performance Study of an Integrated Ammonia Recovery and CarbonCapture Device Based on a Superamphiphobic Membrane

更新时间：2026-10-10

- Performance Study of an Integrated Ammonia Recovery and CarbonCapture Device Based on a Superamphiphobic Membrane
- Chinese Journal of Power Engineering Vol. 46, Issue 2, Pages: 183-192,212(2026)
- 作者机构：
  
  1. 武汉大学动力与机械学院,湖北,武汉,430072
  2. 马克斯·普朗克高分子研究所, 美因茨,55128
  3. 碳排放权交易省部共建协同创新中心,湖北,武汉,430205
  4. 德国马普学会-武汉大学伙伴实验室,湖北,武汉,430072
- 作者简介：
- 基金信息：
- DOI：10.19805/j.cnki.jcspe.2026.240735
  CLC：
- Online First：10 February 2026，
  
  Published：10 February 2026
- 稿件说明：
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王喻宝,王璟,姜伟,陈涛,Hans-Jürgen Butt,秦汉时,侯佑民. 基于超双疏膜的一体化集氨固碳装置性能研究动力工程学报, 2026, 46(2): 183-192,212 https://doi.

org/10.19805/j.cnki.jcspe.2026.240735
王喻宝,王璟,姜伟,陈涛,Hans-Jürgen Butt,秦汉时,侯佑民. 基于超双疏膜的一体化集氨固碳装置性能研究动力工程学报, 2026, 46(2): 183-192,212 https://doi. DOI： 10.19805/j.cnki.jcspe.2026.240735.

org/10.19805/j.cnki.jcspe.2026.240735 DOI：

摘要

针对生物质厌氧发酵过程中沼液与沼气处理工艺中设备复杂、能耗高、耐久性差等问题

设计了一种基于超双疏膜接触器的新型一体化集氨固碳装置

集成了直接接触式膜蒸馏、膜吸收法等多种技术优势

在降低设备复杂性的同时

有效提升了系统工艺流程的能源利用效率。并通过实验系统地研究了一体化装置的氨氮回收和碳捕集性能。结果表明:以低表面张力氨液作为进料液时

膜接触器的液滴接触角大于150°

并在48 h内保持稳定运行;以气体循环式工艺流程运行时

当进料液侧温度达到70 ℃时一体化装置的氨回收率由45%提升至97%

脱除率超过95%

渗透液侧的CO

脱除速率可超过4.3 mol/(m

·h)

实现了沼液和沼气处理过程中的废弃物资源化高效利用。

Abstract

To address the issues of complex equipment

high energy consumption and poor durability in the treatment process of biogas and biogas slurry during anaerobic fermentation of biomass

a new type of integrated ammonia recovery and carbon capture device was designed based on superamphiphobic membrane contactor

which integrated the advantages of direct contact membrane distillation

membrane absorption and other technologies. This device effectively enhances the energy utilization efficiency of the overall process while reducing the complexity of the equipment. The ammonia recovery and carbon capture performances of the integrated device was systematically studied through experiments. Results show that when using ammonia of

low surface tension as feed side

the droplet contact angle of membrane contactor is greater than 150°

and maintains stable operation within 48 h. When operating with a gas circulation process flow and the temperature on the feed liquid side reaches 70 ℃

the ammonia recovery rate of the integrated device is increased from 45% to 97%

and the CO

removal rate exceeds 95%

the CO

removal rate on the permeate side can reach above 4.3 mol/(m

·h)

thus realizing the high-efficiency resource utilization of wastes in the biogas slurry and biogas treatment processes.

关键词

Keywords

references

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