The combustion of high-alkali coal is highly susceptible to severe fouling and slagging issues. Existing research has primarily focused on conventional loads. However
after the boiler drops to low load under deep peak shaving
the mechanisms underlying changes in fouling and NO
x
generation characteristics during highalkali coal combustion remain unclear
necessitating further in-depth investigation. [Methods
]
Targeted experiments were conducted using a muffle furnace and a two-stage drop tube furnace to study the fouling and NO
x
generation characteristics of high-alkali coal combustion under low-load conditions. In the two-stage drop tube furnace experiments
both conventional load and low load conditions were set to simulate actual deep peak-shaving scenarios. [Results
]
The experimental results indicate
that for Hami coal
as the burial depth increases
the occurrence forms of alkali metals in the ash gradually shift from aluminosilicates to sulfates. Moreover
the degree of influence of load variations on the microscopic morphology of ash also diminishes. Compared to conventional loads
under deep peak-shaving low loads
high-alkali coal with high iron
sulfur
and calcium content exhibits enhanced ash melting
increased viscosity
and a greater propensity for fouling(from 14.6 to 16.2 mg/g and from 9.0 to 12.8 mg/g) due to an increase in particles such as sodium and calcium sulfate on the ash surface. In contrast
high-alkali coal with high silicon and aluminum content shows little change in the number of sticky particles on the ash surface
resulting in a smaller or even reduced propensity for fouling(from 12.9 to 6.7 mg/g)
as most of the free sodium is captured by silicon or aluminum
and the release of calcium is suppressed. Furthermore
under deep peak-shaving low loads
the nitrogen conversion rate of high-alkali coal combustion generally increases by approximately 7%. However
for coal types with higher volatile matter content(30%)
the nitrogen conversion rate could decrease. This could be attributed to the organic volatiles released during combustion
which are difficult to fully burn at lower temperatures
leading to a significant decline in combustion efficiency. [Conclusion
]
When a boiler shifts from conventional load operation to deep peak-shaving under low-load conditions
priority should be given to selecting coal types with higher volatile matter content and higher levels of silicon and aluminum to ensure the safety and reliability of unit operation.