YANG Jianbo, LIU Haiyu, SHI Xiaohan, et al. Experimental study on denitration performance of manganese loaded activated coke under microwave irradiation[J]. Thermal power generation, 2021, 50(6): 163-168.
DOI:
YANG Jianbo, LIU Haiyu, SHI Xiaohan, et al. Experimental study on denitration performance of manganese loaded activated coke under microwave irradiation[J]. Thermal power generation, 2021, 50(6): 163-168. DOI: 10.19666/j.rlfd.202009270.
Experimental study on denitration performance of manganese loaded activated coke under microwave irradiation
摘要
通过在活性焦上负载Mn_2O_3实现微波低功率(200W)高效脱除NO。实验发现
经硝酸氧化处理和负载Mn_2O_3
活性焦表面的羰基和羧基等含氧官能团含量增加
微波辐照使得活性焦比表面积和微孔体积大幅增加
为反应气体在活性焦表面吸附提供丰富的表面活性位
有利于NO的脱除。硝酸处理后的活性焦负载Mn_2O_3
脱硝效率能稳定达到85%以上
负载Mn_2O_3使得微波诱导的放电强度增强
等离子体浓度增加
更多的稳定态NO分子被转化为激发态
促进了NO还原反应的发生。
Abstract
In this paper
Mn_2O_3-loaded activated coke was used to remove NO efficiently at low microwave power(200 W). The experimental results show that
nitric acid oxidation treatment and loading of Mn_2O_3 increased the content of oxygen-containing functional groups of the activated coke such as carbonyl and carboxyl groups. Microwave irradiation significantly increased the specific surface area and micropore volume of the activated coke
and provides a rich surface for reactive gas adsorption on the activated coke. It was conducive to the removal of NO. After the nitric acid treatment
the denitration efficiency of Mn_2O_3-loaded activated coke could stably reach higher than 85%. The loading of Mn_2O_3 increased the intensity of microwave-induced discharge and the plasma concentration
so that more stable NO molecules were excited
which promoted the occurrence of C-NO reduction reactions.