ZHOU Guomin, ZHANG Qi, CHEN Liping, et al. High-temperature and medium-speed pyrolysis characteristics of Shenhua bituminous coal on fixed bed[J]. Thermal power generation, 2020, 49(6): 134-143.
DOI:
ZHOU Guomin, ZHANG Qi, CHEN Liping, et al. High-temperature and medium-speed pyrolysis characteristics of Shenhua bituminous coal on fixed bed[J]. Thermal power generation, 2020, 49(6): 134-143. DOI: 10.19666/j.rlfd.201912255.
High-temperature and medium-speed pyrolysis characteristics of Shenhua bituminous coal on fixed bed
摘要
本文研究了中速热解过程中神华烟煤的组分析出规律
基于管式炉获得了不同热解压力和温度情况下神华烟煤的热解产物
分析了其热解机理。同时
对热解组分分布、产量和热解失重率规律进行研究。结果表明:在高升温速率下(可达100 K/s)
热解失重率随热解温度的升高而不断增加
随热解压力升高而降低;热解气组分以H_2和CO为主
CH_4和CO_2次之
C_3H_8和O_2含量几乎接近于零
析出顺序不尽相同
析出曲线表现为单峰或双峰分布;热解压力会对组分析出峰产生较大的影响;热解气产量随热解温度升高而增大
但其与热解压力呈非线性的变化关系。
Abstract
The precipitation rules of components in Shenhua bituminous coal during medium speed pyrolysis was analyzed.On the basis of a tube furnace
the pyrolysis products of Shenhua bituminous coal at different temperatures and pressures were obtained
and the pyrolysis mechanism was investigated.Moreover
the pyrolysis components distribution
yields and weight loss rules during pyrolysis were also researched.The results show that
at high heating rate(up to 100 K/s)
the weight loss rate increased with the pyrolysis temperature
and decreased as the pyrolysis pressure increased.The main components of the pyrolysis gas were H_2 and CO
then were CH_4 and CO_2
and the content of C_3H_8 and O_2 was almost zero
and their order of precipitation was different.The precipitation curves of all light components showed unimodal or bimodal distribution with a certain peak width.The pyrolysis pressure had a relatively great influence on the precipitation peak of the component.The total yield of the pyrolysis gas increased with the pyrolysis temperature
but it had a nonlinear relationship with the pyrolysis pressure..