To improve the accuracy and efficiency of the aging life prediction and assessment of transformer oil-paper insulation

and to make up for the deficiencies of traditional characterizers

such as 2-furfural

carbon monoxide

and carbon dioxide

a method for the simultaneous determination of methanol

ethanol

$n-\mathbf{propanol}$

and

$n$

-butanol in oil with a single injection is established by headspace-gas chromatography-mass spectrometry. The measured results show that the determination limits of the four alcohol characterizers can be controlled to

$\mathbf{10}\ \mu \mathbf{g}/\mathbf{kg}$

level. Based on this method

the change patterns of the above four alcohols with thermal aging time and degree of polymerization are obtained through thermal aging experimental research. Ethanol

$n$

-propanol

and

$n$

-butanol in oil indicate nearly linear correlations with thermal aging time and degree of polymerization

similar to that of methanol. By analyzing 52 sets of measured data of 500 kV EHV transformers in operation

$n$

-butanol is found to have excellent performance

and a new method t

o evaluate the aging state of oil-paper insulation employing

$n$

-butanol and methanol is proposed along with the aging attention value model. The measured data of 500 kV EHV transformers in operation indicate that the combination of

$n$

-butanol and methanol as the preferred characterizers can effectively compensate for the shortcoming of traditional characterizers in the early stages of aging

and the feasibility of the method is verified. Two possible pathways for the generation of

$n$

-butanol by cellulose cleavage during the aging of oil-paper are proposed from the chemical structure of cellulose.